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Formic acid, cyclohexyl ester

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Ttriple201.33KN/AKabo, Kozyro, et al., 1999Uncertainty assigned by TRC = 0.15 K; TRC
Quantity Value Units Method Reference Comment
Deltavap49.3 ± 0.2kJ/molCPaulechka, Zaitsau, et al., 2004See also Zaitsau, Verevkin, et al., 2003.; AC
Deltavap52.0 ± 1.3kJ/molMEZaitsau, Verevkin, et al., 2003Based on data from 243. - 273. K.; AC
Deltavap49.5 ± 1.2kJ/molMEZaitsau, Verevkin, et al., 2003Based on data from 243. - 273. K.; AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Reference Comment
47.1322.Steyer and Sundmacher, 2005Based on data from 307. - 434. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
10.49201.3Kabo, Kozyro, et al., 1999, 2AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kabo, Kozyro, et al., 1999
Kabo, G.J. (see Kabo; Kozyro, A.A.; Frenkel, M. (see frenke ml); Blokhin, A.V., Solid Phase Transitions of the Cyclohexane Derivatives and the Model of Energy States of Molecules in Plastic Crystals, Mol. Cryst. Liq. Cryst., 1999, 326, 333-5. [all data]

Paulechka, Zaitsau, et al., 2004
Paulechka, Y.U.; Zaitsau, Dz.H.; Kabo, G.J., On the difference between isobaric and isochoric heat capacities of liquid cyclohexyl esters, Journal of Molecular Liquids, 2004, 115, 2-3, 105-111, https://doi.org/10.1016/j.molliq.2004.03.002 . [all data]

Zaitsau, Verevkin, et al., 2003
Zaitsau, Dzmitry H.; Verevkin, Sergey P.; Paulechka, Yauheni U.; Kabo, Gennady J.; Sevruk, Viktor M., Comprehensive Study of Vapor Pressures and Enthalpies of Vaporization of Cyclohexyl Esters, J. Chem. Eng. Data, 2003, 48, 6, 1393-1400, https://doi.org/10.1021/je025634v . [all data]

Steyer and Sundmacher, 2005
Steyer, Frank; Sundmacher, Kai, VLE and LLE Data Set for the System Cyclohexane + Cyclohexene + Water + Cyclohexanol + Formic Acid + Formic Acid Cyclohexyl Ester, J. Chem. Eng. Data, 2005, 50, 4, 1277-1282, https://doi.org/10.1021/je050023z . [all data]

Kabo, Kozyro, et al., 1999, 2
Kabo, G.J.; Kozyro, A.A.; Frenkel, M.; Blokhin, A.V., Solid Phase Transitions of the Cyclohexane Derivatives and the Model of Energy States of Molecules in Plastic Crystals, Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, 1999, 326, 1, 333-355, https://doi.org/10.1080/10587259908025424 . [all data]


Notes

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