2,4-Heptadienal, (E,E)-


Normal alkane RI, non-polar column, temperature ramp

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5 MSVF-5 MSHP-5OV-1HP-5
Column length (m) 30.30.60.50.30.
Carrier gas HeliumHeliumHelium Helium
Substrate      
Column diameter (mm) 0.250.250.250.320.32
Phase thickness (μm) 0.250.250.250.500.25
Tstart (C) 50.40.35.40.60.
Tend (C) 250.250.220.270.240.
Heat rate (K/min) 5.5.10.2.3.
Initial hold (min) 0.53.1. 2.
Final hold (min) 0.53.15.10. 
I 1011.1017.1011.981.1013.
ReferenceFanaro, Duarte, et al., 2012Liu, Lu, et al., 2011Piyachaiseth, Jirapakkul, et al., 2011Da Costa, Yang, et al., 2010Kahriman, Tosun, et al., 2010
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5 MSHP-5 MSHP-5HP-5 MSHP-5 MS
Column length (m) 30.30.30.30.30.
Carrier gas HeliumHeliumHydrogenHeliumHelium
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 70.70.70.70.35.
Tend (C) 290.290.290.290.195.
Heat rate (K/min) 5.5.5.5.2.
Initial hold (min)     5.
Final hold (min)  10. 10.30.
I 1012.1013.1014.1012.1010.
ReferenceLazarevic, Radulovic, et al., 2010Radulovic, Blagojevic, et al., 2010Radulovic, Dordevic, et al., 2010Radulovic, Dordevic, et al., 2010, 2Kim and Chung, 2009
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5 MSMega 5 MSHP-5 MSHP-5 MSDB-1
Column length (m) 30.60.30.30.30.
Carrier gas HeliumHeliumHeliumHeliumHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 70.40.50.50.30.
Tend (C) 290.240.280.230.210.
Heat rate (K/min) 5.3.4.4.5.
Initial hold (min)  2. 4. 
Final hold (min) 10.  10. 
I 1014.1011.1010.1011.990.
ReferenceRadulovic, Blagojevic, et al., 2009Romeo, Verzera, et al., 2009Zhao, Zeng, et al., 2009Forero, Quijano, et al., 2008Kumazawa, Itobe, et al., 2008
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5 MSHP-5PE-5DB-5
Column length (m) 10.30.30.50.30.
Carrier gas HeliumHeliumHeliumHeHe
Substrate      
Column diameter (mm) 0.100.250.320.320.25
Phase thickness (μm) 0.400.250.250.250.25
Tstart (C) 40.50.60.100.40.
Tend (C) 280.250.260.280.260.
Heat rate (K/min) 20.6.55.3.2.
Initial hold (min) 1.1.52.1.5.
Final hold (min) 1.10.13. 20.
I 1023.1020.997.1018.1015.
ReferenceMildner-Szkudlarz and Jelen, 2008Thakeow, Angeli, et al., 2008Kucuk, Gulec, et al., 2006Pandey-Rai S., Mallavarapu G.R., et al., 2006Senatore, Landolfi, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase MDN-5DB-5HP-5MSHP-5DB-5
Column length (m) 60.30.30.30.60.
Carrier gas HeHeHeHeliumHe
Substrate      
Column diameter (mm) 0.250.250.250.320.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.40.60.40.35.
Tend (C) 270.260.280.300.280.
Heat rate (K/min) 4.2.3.4.5.
Initial hold (min) 4.5.  2.
Final hold (min) 5.20. 5.4.
I 1014.1015.1006.996.1006.
Referencevan Loon, Linssen, et al., 2005Senatore, Apostolides Arnold, et al., 2005Slavkovska, Couladis, et al., 2005Utsunomia, Kawata, et al., 2005Dhanda, Pegg, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase MDN-5DB-5HP-1SPB-1SPB-1
Column length (m) 30.30.50.30.30.
Carrier gas HeH2HeHeHe
Substrate      
Column diameter (mm) 0.250.30.20.250.25
Phase thickness (μm) 0.250.250.50.250.25
Tstart (C) 40.35.60.40.40.
Tend (C) 280.240.220.200.200.
Heat rate (K/min) 20.8.2.3.3.
Initial hold (min) 1.2.5 10.10.
Final hold (min) 1.2.40.  
I 1023.994.974.981.973.
ReferenceMildner-Szkudlarz, Jelen, et al., 2003Triqui and Bouchriti, 2003Valette, Fernandez, et al., 2003Vichi, Pizzale, et al., 2003Vichi, Pizzale, et al., 2003, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5RSL-200DB-5SPB-5Optima-1
Column length (m) 30.30.30.30.25.
Carrier gas HeH2HeHeliumHe
Substrate      
Column diameter (mm) 0.250.250.250.250.20
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.40.60.60.50.
Tend (C) 240.280.240.250.250.
Heat rate (K/min) 3.6.3.4.3.
Initial hold (min)  2. 2.3.
Final hold (min)  10. 20. 
I 1016.978.1010.998.991.
ReferenceFlamini, Ertugrul, et al., 2002Jirovetz, Smith, et al., 2002Kobaisy, Tellez, et al., 2002Pino, Marbot, et al., 2002Brun, Bessière, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5DB-5SE-54OV-101OV-101
Column length (m) 30.30.30.50.50.
Carrier gas N2He N2N2
Substrate      
Column diameter (mm) 0.250.250.520.250.25
Phase thickness (μm) 0.250.251.5  
Tstart (C) 60.60.5.80.80.
Tend (C) 220.240.230.200.200.
Heat rate (K/min) 5.3.6.2.2.
Initial hold (min) 10.    
Final hold (min)      
I 1017.1010.1011.980.983.
ReferenceCampeol, Flamini, et al., 2001Tellez, Dayan, et al., 2000Milo and Grosch, 1996Tamura, Nakamoto, et al., 1995Tamura, Nakamoto, et al., 1995
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5 MSDB-1DB-5DB-5DB-1
Column length (m) 30.60.60.60. 
Carrier gas Helium  He 
Substrate      
Column diameter (mm) 0.250.320.250.25 
Phase thickness (μm)   0.25  
Tstart (C) 50.30.40.40.50.
Tend (C) 250.200.250.160.230.
Heat rate (K/min) 4.4.2.2.4.
Initial hold (min)  25.5.5. 
Final hold (min)  20.  10.
I 998.979.1010.1016.979.
ReferenceGomez and Ledbetter, 1994Hansen, Buttery, et al., 1992Lee, Macku, et al., 1991Macku and Shibamoto, 1991Binder, Turner, et al., 1990
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101OV-101OV-101OV-101SE-30
Column length (m) 50.50.50.50.50.
Carrier gas NitrogenNitrogenN2N2 
Substrate      
Column diameter (mm) 0.250.250.250.250.5
Phase thickness (μm)      
Tstart (C) 70.80.80.80.40.
Tend (C) 200.200.200.200.170.
Heat rate (K/min) 2.2.2.2.3.
Initial hold (min)     3.
Final hold (min)      
I 981.982.982.984.983.
ReferenceSugisawa, Nakamura, et al., 1990Sugisawa, Nakamura, et al., 1990Yang and Sugisawa, 1990Yang and Sugisawa, 1990Heydanek and McGorrin, 1981
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Fanaro, Duarte, et al., 2012
Fanaro, G.B.; Duarte, R.C.; Santillo, A.G.; Pinto e Silva, M.E.M.; Purgatto, E.; Villavicento, A.L.C.H., Evaluation of γ-radiation on oolong tea odor volatiles, Radiation Phys. Chem., 2012, 81, 8, 1152-1156, https://doi.org/10.1016/j.radphyschem.2011.11.061 . [all data]

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Da Costa, Yang, et al., 2010
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Kahriman, Tosun, et al., 2010
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Lazarevic, Radulovic, et al., 2010
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Radulovic, Blagojevic, et al., 2010
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Radulovic, Dordevic, et al., 2010
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Kim and Chung, 2009
Kim, J.-S.; Chung, H.Y., GC-MS analysis of the volatile components in dried boxthorn (Lycium chimensis) Fruit, J. Korean Soc. Appl. Biol. Chem., 2009, 52, 5, 516-524, https://doi.org/10.3839/jksabc.2009.088 . [all data]

Radulovic, Blagojevic, et al., 2009
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Romeo, Verzera, et al., 2009
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Forero, Quijano, et al., 2008
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van Loon, Linssen, et al., 2005
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Kobaisy, Tellez, et al., 2002
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Campeol, Flamini, et al., 2001
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Tellez, Dayan, et al., 2000
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Milo, C.; Grosch, W., Changes in the odorants of boiled salmon and cod as affected by the storage of the raw material, J. Agric. Food Chem., 1996, 44, 8, 2366-2371, https://doi.org/10.1021/jf9507203 . [all data]

Tamura, Nakamoto, et al., 1995
Tamura, H.; Nakamoto, H.; Yang, R.-H.; Sugisawa, H., Characteristic aroma compounds in green algae (Ulva pertusa) volatiles, Nippon Shokuhin Kagaku Kogaku Kaishi, 1995, 42, 11, 887-891, https://doi.org/10.3136/nskkk.42.887 . [all data]

Gomez and Ledbetter, 1994
Gomez, E.; Ledbetter, C.A., Comparative study of the aromatic profiles of two different plum species: Prunus salicina Lindl and Prunus simonii L., J. Sci. Food Agric., 1994, 65, 1, 111-115, https://doi.org/10.1002/jsfa.2740650116 . [all data]

Hansen, Buttery, et al., 1992
Hansen, M.; Buttery, R.G.; Stern, D.J.; Cantwell, M.I.; Ling, L.C., Broccoli storage under low-oxygen atmosphere: Identification of higher boiling volatiles, J. Agric. Food Chem., 1992, 40, 5, 850-852, https://doi.org/10.1021/jf00017a029 . [all data]

Lee, Macku, et al., 1991
Lee, S.-R.; Macku, C.; Shibamoto, T., Isolation and identification of headspace volatiles formed in heated butter, J. Agric. Food Chem., 1991, 39, 11, 1972-1975, https://doi.org/10.1021/jf00011a017 . [all data]

Macku and Shibamoto, 1991
Macku, C.; Shibamoto, T., Headspace volatile compounds formed from heated corn oil and corn oil with glycine, J. Agric. Food Chem., 1991, 39, 7, 1265-1269, https://doi.org/10.1021/jf00007a014 . [all data]

Binder, Turner, et al., 1990
Binder, R.G.; Turner, C.E.; Flath, R.A., Volatile components of purple starthistle, J. Agric. Food Chem., 1990, 38, 4, 1053-1055, https://doi.org/10.1021/jf00094a030 . [all data]

Sugisawa, Nakamura, et al., 1990
Sugisawa, H.; Nakamura, K.; Tamura, H., The aroma profile of the volatile in marine green algae (Ulva pertusa), Food Reviews International, 1990, 6, 4, 573-589, https://doi.org/10.1080/87559129009540893 . [all data]

Yang and Sugisawa, 1990
Yang, R.; Sugisawa, H., Citrus Suachi Hort. ex Shirai. Volatile components in Sudachi (Citrus Sudachi Hort. ex Shirai) juice, Nippon Shokuhin Kogyo Gakkaishi, 1990, 37, 12, 946-952, https://doi.org/10.3136/nskkk1962.37.12_946 . [all data]

Heydanek and McGorrin, 1981
Heydanek, M.G.; McGorrin, R.J., Gas chromatography-mass spectroscopy identification of volatiles from rancid oat groats, J. Agric. Food Chem., 1981, 29, 5, 1093-1095, https://doi.org/10.1021/jf00107a051 . [all data]


Notes

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References