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Methyl(trifluoromethyl) sulfide


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
9.90 ± 0.02PIHagenow, Jochims, et al., 1989LL
9.75 ± 0.11EICullen, Frost, et al., 1970RDSH
9.88 ± 0.03PECullen, Frost, et al., 1969RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CFS+14.20 ± 0.05CH2F+HFPIHagenow, Jochims, et al., 1989LL
CFS+15.32 ± 0.13?EICullen, Frost, et al., 1970RDSH
CF2S+13.4 ± 0.1CH3FPIHagenow, Jochims, et al., 1989LL
CF3+12.75 ± 0.05CH3SPIHagenow, Jochims, et al., 1989LL
CF3+13.07 ± 0.09?EICullen, Frost, et al., 1970RDSH
CHS+14.88 ± 0.06?EICullen, Frost, et al., 1970RDSH
CH2S+~14.?EICullen, Frost, et al., 1970RDSH
CH3+14.1 ± 0.1SCF3PIHagenow, Jochims, et al., 1989LL
CH3+14.24?EICullen, Frost, et al., 1970RDSH
CH3S+11.70 ± 0.05CF3PIHagenow, Jochims, et al., 1989LL
CH3S+11.78 ± 0.03?EICullen, Frost, et al., 1970RDSH
C2H3F2S+14.45 ± 0.05FPIHagenow, Jochims, et al., 1989LL
C2H3F2S+15.7 ± 0.24FEICullen, Frost, et al., 1970RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hagenow, Jochims, et al., 1989
Hagenow, G.; Jochims, H.-W.; Sawatzki, J.; Minkwitz, R.; Baumgartel, H., Photoionisationsmassenspektren von methyl(trifluormethyl)sulfan CH3SCF3, Z. Naturforsch. B:, 1989, 44, 17. [all data]

Cullen, Frost, et al., 1970
Cullen, W.R.; Frost, D.C.; Pun, M.T., Mass spectra, appearance potentials, heats of formation, and bond energies of some alkyl and perfluoroalkyl sulfides, Inorg. Chem., 1970, 9, 1976. [all data]

Cullen, Frost, et al., 1969
Cullen, W.R.; Frost, D.C.; Vroom, D.A., Ionization potentials of some sulfur compounds, Inorg. Chem., 1969, 8, 1803. [all data]


Notes

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