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Thiocarbonyl fluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to CF2S+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
10.3EIBinnewies, Grosse, et al., 1985LBLHLM
10.52PEMines, Thomas, et al., 1973LLK
10.53 ± 0.10EIHildenbrand, 1973LLK
10.45 ± 0.01PEKroto and Suffolk, 1972LLK
10.64PEWittel, Hass, et al., 1972Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Binnewies, Grosse, et al., 1985
Binnewies, M.; Grosse, J.; Le Van, D., Reaktive E=C(p-p)«pi»-systeme II: Massenspektrometrische untersuchun von F3CP=CF2, F3CAs=CF2, S=CF2 und Se=CF2, Phosphorus Sulfur, 1985, 21, 349. [all data]

Mines, Thomas, et al., 1973
Mines, G.W.; Thomas, R.K.; Thompson, H., The photoelectron spectra of thiocarbonyl fluoride and thiocarbonyl chloride, Proc. R. Soc. London A:, 1973, 333, 171. [all data]

Hildenbrand, 1973
Hildenbrand, D.L., Mass spectrometric studies of some gaseous sulfur fluorides, J. Phys. Chem., 1973, 77, 897. [all data]

Kroto and Suffolk, 1972
Kroto, H.W.; Suffolk, R.J., The photoelectron spectrum of and F2CS fluorine substitution shifts, Chem. Phys. Lett., 1972, 17, 213. [all data]

Wittel, Hass, et al., 1972
Wittel, K.; Hass, A.; Bock, H., Photoelektronenspektren und molekuleigenschaften, XVI. Thiocarbonylhalogenide-orbitale und ladungen, Chem. Ber., 1972, 105, 3865. [all data]


Notes

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