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2-Butenal

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil375.50KN/AMarkovnik, Sachek, et al., 1979Uncertainty assigned by TRC = 0.02 K; TRC
Tboil375.5KN/AAnonymous, 1953Uncertainty assigned by TRC = 0.6 K; TRC
Tboil363.15KN/AMiller, Cook, et al., 1950Uncertainty assigned by TRC = 5. K; TRC
Tboil377.2KN/ATimmermans, 1922Uncertainty assigned by TRC = 0.3 K; TRC
Tboil375.3KN/ATimmermans, 1913Uncertainty assigned by TRC = 1.5 K; TRC
Quantity Value Units Method Reference Comment
Tfus198.KN/AAnonymous, 1968Uncertainty assigned by TRC = 5. K; TRC
Tfus196.7KN/ATimmermans, 1922Uncertainty assigned by TRC = 0.5 K; TRC
Tfus199.15KN/ATimmermans, 1913Uncertainty assigned by TRC = 1.5 K; TRC
Quantity Value Units Method Reference Comment
Tc601.98KN/AGurarii, Kuleshov, et al., 1987Uncertainty assigned by TRC = 0.1 K; TRC
Quantity Value Units Method Reference Comment
Pc54.969barN/AGurarii, Kuleshov, et al., 1987Uncertainty assigned by TRC = 0.01 bar; TRC
Quantity Value Units Method Reference Comment
rhoc4.1803mol/lN/AGurarii, Kuleshov, et al., 1987Uncertainty assigned by TRC = 0.04 mol/l; TRC
Quantity Value Units Method Reference Comment
Deltavap37.3 ± 0.4kJ/molCVan-chin-syan, Kochubei, et al., 1996ALS
Deltavap37.2kJ/molN/AVan-chin-syan, Kochubei, et al., 1996DRB
Deltavap37.3 ± 0.4kJ/molCVan-Chin-Syan, Kochubei, et al., 1996AC
Deltavap38. ± 0.8kJ/molEDolliver, Gresham, et al., 1938Heat of formation derived by Cox and Pilcher, 1970; ALS
Deltavap38.1kJ/molN/ADolliver, Gresham, et al., 1938DRB

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
38.8325.EBWiberg, Morgan, et al., 1994AC
35.1 ± 0.5332.N/ABaglay, Gurariy, et al., 1988Based on data from 288. - 376. K.; AC
36.8321.AStephenson and Malanowski, 1987Based on data from 306. - 376. K. See also Waradzin and Skubla, 1973 and Boublik, Fried, et al., 1984.; AC
37.3319.N/AMarkovnik, Sachek, et al., 1979Based on data from 304. - 377. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Markovnik, Sachek, et al., 1979
Markovnik, V.S.; Sachek, A.I.; Peshchenko, A.D.; Shvaro, O.V.; Andreevskii, D.N.; Olizarevich, N.M., Termodin. Org. Soedin., 1979, 107. [all data]

Anonymous, 1953
Anonymous, R., , Physical Properties of Chemical Substances, Dow Chemical Company, 1953. [all data]

Miller, Cook, et al., 1950
Miller, A.L.; Cook, N.C.; Whitmore, F.C., The Ketonic Decarboxylation Reaction: The Ketonic Decarboxylation of Trimethylacetic Acid and Isobutyric Acid, J. Am. Chem. Soc., 1950, 72, 2732. [all data]

Timmermans, 1922
Timmermans, J., Investigation of the Freezing Point of Organic Substances VII, Bull. Soc. Chim. Belg., 1922, 31, 389. [all data]

Timmermans, 1913
Timmermans, J., Bull. Soc. Chim. Belg., 1913, 27, 334. [all data]

Anonymous, 1968
Anonymous, X., Chemicals and Plastics Physical Properties, 1968, Union Carbide Corp., product bulletin, 1968. [all data]

Gurarii, Kuleshov, et al., 1987
Gurarii, L.L.; Kuleshov, G.G.; Baglai, A.K.; Petrashkevich, R.I., Thermodynamic properties of 2-methoxypropene, Khim.-Farm. Zh., 1987, 21, 247. [all data]

Van-chin-syan, Kochubei, et al., 1996
Van-chin-syan, Yu.Ya.; Kochubei, V.V.; Sergeev, V.V.; Raevskii, Yu.A.; Gerasimchuk, S.I.; Kotovich, Kh.Z., Thermodynamic properties of some acids and aldehydes of the acrylic series, Sov. J. Chem. Phys. (Engl. Transl.), 1996, 70, 1789-1794, In original 1932. [all data]

Van-Chin-Syan, Kochubei, et al., 1996
Van-Chin-Syan, Yu.Ya.; Kochubei, V.V.; Sergeev, V.V.; Raevskii, Yu.A.; Gerasimchuk, S.I.; Kotovich, Kh.Z., Thermodynamic properties of some acrylic-series acids and aldehydes, Zh. Fiz. Khim., 1996, 70, 11, 1932. [all data]

Dolliver, Gresham, et al., 1938
Dolliver, M.A.; Gresham, T.L.; Kistiakowsky, G.B.; Smith, E.A.; Vaughan, W.E., Heats of organic reactions. VI. Heats of hydrogenation of some oxygen-containing compounds, J. Am. Chem. Soc., 1938, 60, 440-450. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Wiberg, Morgan, et al., 1994
Wiberg, K.B.; Morgan, K.M.; Maltz, H., Thermochemistry of carbonyl reactions. 6. A study of hydration equilibria, J. Am. Chem. Soc., 1994, 116, 11067-11077. [all data]

Baglay, Gurariy, et al., 1988
Baglay, A.K.; Gurariy, L.L.; Kuleshov, G.G., Physical properties of compounds used in vitamin synthesis, J. Chem. Eng. Data, 1988, 33, 512-518. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Waradzin and Skubla, 1973
Waradzin, W.; Skubla, P., Chem. Prum., 1973, 23, 11, 556. [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]


Notes

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