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2-Silaisobutene


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Fluorine anion + 2-Silaisobutene = (Fluorine anion bullet 2-Silaisobutene)

By formula: F- + C3H8Si = (F- bullet C3H8Si)

Quantity Value Units Method Reference Comment
Deltar150. ± 8.kJ/molICRAllison and McMahon, 1990gas phase; bracketing

Iron ion (1+) + 2-Silaisobutene = (Iron ion (1+) bullet 2-Silaisobutene)

By formula: Fe+ + C3H8Si = (Fe+ bullet C3H8Si)

Quantity Value Units Method Reference Comment
Deltar270. ± 40.kJ/molICRJacobson and Bakhtiar, 1993gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Allison and McMahon, 1990
Allison, C.E.; McMahon, T.B., How Strong is the Si=C Bond in Fluoro- and Methyl Substituted Silaethylenes? An Experimental Determination of Pi Bond Strengths, J. Am. Chem. Soc., 1990, 112, 5, 1672, https://doi.org/10.1021/ja00161a002 . [all data]

Jacobson and Bakhtiar, 1993
Jacobson, D.B.; Bakhtiar, R., Generation, Characterization and Properties of Iron-Silylene and Iron-Sylene Cationic Complexes in the Gas Phase, J. Am. Chem. Soc., 1993, 115, 23, 10830, https://doi.org/10.1021/ja00076a046 . [all data]


Notes

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