BrONO2


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias and Joel F. Liebman

Ionization energy determinations

IE (eV) Method Reference
10.60PEDianxum and Peng, 1996

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
BrO+11.62NO2PIJochims, Denzer, et al., 1992 
NO+13.1BrO+O/Br+O2PIJochims, Denzer, et al., 1992 
NO2+10.6BrOPIJochims, Denzer, et al., 1992 
NO2+13.2Br+OPIJochims, Denzer, et al., 1992 

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 NO2 a-stretch 1714 vs gas IR Wilson and Christe, 1987
1 NO2 a-stretch 1709 vs Ne IR Wilson and Christe, 1987
1 NO2 a-stretch 1702 vs N2 IR Wilson and Christe, 1987
2 NO2 s-stretch 1288 vs gas IR Wilson and Christe, 1987
2 NO2 s-stretch 1285 vs Ne IR Wilson and Christe, 1987
2 NO2 s-stretch 1285 vs N2 IR Wilson and Christe, 1987
3 NO2 scissors 806 vs gas IR Wilson and Christe, 1987
3 NO2 scissors 802 vs Ne IR Wilson and Christe, 1987
3 NO2 scissors 805 vs N2 IR Wilson and Christe, 1987
4 OBr stretch 750 w Ne IR Wilson and Christe, 1987
4 OBr stretch 750 w N2 IR Wilson and Christe, 1987
5 NO2 rock 564 s gas IR Wilson and Christe, 1987
5 NO2 rock 563 s Ne IR Wilson and Christe, 1987
5 NO2 rock 574 s N2 IR Wilson and Christe, 1987
5 NO2 rock 569 s N2 IR Wilson and Christe, 1987
a 8 ONO2 OPLA 728 w m gas IR Wilson and Christe, 1987
8 ONO2 OPLA 723 w Ne IR Wilson and Christe, 1987
8 ONO2 OPLA 725 w m N2 IR Wilson and Christe, 1987

Additional references: Jacox, 1994, page 289; Jacox, 1998, page 303; Casper, Lambotte, et al., 1993

Notes

wWeak
mMedium
sStrong
vsVery strong

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dianxum and Peng, 1996
Dianxum, W.; Peng, J., He I photoelectron spectroscopy study on the electronic structure of bromine nitrate, BrONO2, J. Phys. Chem., 1996, 100, 4382. [all data]

Jochims, Denzer, et al., 1992
Jochims, H.-W.; Denzer, W.; Baumgartel, H.; Losking, O.; Willner, H., Photochemical decay reactions of N2O5, HNO3, ClNO3 and BrNO3 in the energy range 10-20 eV, Ber. Bunsen-Ges. Phys. Chem., 1992, 96, 573. [all data]

Wilson and Christe, 1987
Wilson, W.W.; Christe, K.O., Bromine nitrates, Inorg. Chem., 1987, 26, 10, 1573, https://doi.org/10.1021/ic00257a022 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Casper, Lambotte, et al., 1993
Casper, B.; Lambotte, P.; Minkwitz, R.; Oberhammer, H., Gas-phase structures of chlorine and bromine nitrate (ClONO2 and BrONO2), J. Phys. Chem., 1993, 97, 39, 9992, https://doi.org/10.1021/j100141a017 . [all data]


Notes

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