Thiophosphoryl chloride


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Takehiko Shimanouchi

Symmetry:   C3nu     Symmetry Number sigma = 3


 Sym.   No   Approximate   Selected Freq.  Infrared   Raman   Comments 
 Species   type of mode   Value   Rating   Value  Phase  Value  Phase

a1 1 PS str 767  B 770 gas 767.2 p gas
a1 2 PCl3 s-str 432  B 431 gas 431.6 p gas
a1 3 PCl3 s-deform 246  C 252 gas 246.0 dp gas OV(«nu»5)
e 4 PCl3 d-str 544  C 547 gas 543.7 dp gas
e 5 PCl3 d-deform 246  C 252 gas 246 dp gas OV(«nu»3)
e 6 PCl3 rock 167  C 174 liq. 167.3 dp gas

Source: Shimanouchi, 1972

Notes

pPolarized
dpDepolarized
OVOverlapped by band indicated in parentheses.
B1~3 cm-1 uncertainty
C3~6 cm-1 uncertainty

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Shimanouchi, 1972
Shimanouchi, T., Tables of Molecular Vibrational Frequencies Consolidated Volume II, J. Phys. Chem. Ref. Data, 1972, 6, 3, 993-1102. [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References