1-Methyl ethoxy radical

• Formula: C₃H₇O
• Molecular weight: 59.0871
• IUPAC Standard InChI: InChI=1S/C3H7O/c1-3(2)4/h3H,1-2H3 Copy

  
• IUPAC Standard InChIKey: ZOAMZFNAPHWBEN-UHFFFAOYSA-N Copy
• CAS Registry Number: 3958-66-5
• Chemical structure:
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• Information on this page:
  • Gas phase ion energetics data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to C₃H₇O⁺ (ion structure unspecified)

Electron affinity determinations

Ionization energy determinations

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B

State:   A

State:   X

Additional references: Jacox, 1994, page 416; Jacox, 2003, page 391; Gopalakrishnan, Zu, et al., 2003

Notes

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ramond, Davico, et al., 2000
Ramond, T.M.; Davico, G.E.; Schwartz, R.L.; Lineberger, W.C., Vibronic structure of alkoxy radicals via photoelectron spectroscopy, J. Chem. Phys., 2000, 112, 3, 1158-1169, https://doi.org/10.1063/1.480767 . [all data]

Ellison, Engleking, et al., 1982
Ellison, G.B.; Engleking, P.C.; Lineberger, W.C., Photoelectron spectroscopy of alkoxide and enolate negative ions, J. Phys. Chem., 1982, 86, 4873. [all data]

Bartmess, Scott, et al., 1979
Bartmess, J.E.; Scott, J.A.; McIver, R.T., Jr., The gas phase acidity scale from methanol to phenol, J. Am. Chem. Soc., 1979, 101, 6047. [all data]

Williams and Hamill, 1968
Williams, J.M.; Hamill, W.H., Ionization potentials of molecules and free radicals and appearance potentials by electron impact in the mass spectrometer, J. Chem. Phys., 1968, 49, 4467. [all data]

Trepka and Neuert, 1963
Trepka, L.v.; Neuert, H., Uber die Entstehenung von Negativen Ionen aus einigen Kohlenwasserstoffen und Alkoholen durch Elektronenstoss, Z. Naturfor., 1963, 18A, 1295. [all data]

Page and Goode, 1969
Page, F.M.; Goode, G.C., Negative Ions and the Magnetron., Wiley, NY, 1969. [all data]

Ohbayashi, Akimoto, et al., 1977
Ohbayashi, K.; Akimoto, H.; Tanaka, I., Emission spectra of methoxyl, ethoxyl, and isopropoxyl radicals, J. Phys. Chem., 1977, 81, 8, 798, https://doi.org/10.1021/j100523a023 . [all data]

Balla, Nelson, et al., 1985
Balla, R.J.; Nelson, H.H.; McDonald, J.R., Kinetics of the reactions of isopropoxy radicals with NO, NO2, and O2, Chem. Phys., 1985, 99, 2, 323, https://doi.org/10.1016/0301-0104(85)80129-4 . [all data]

Foster, Hsu, et al., 1986
Foster, S.C.; Hsu, Y.-C.; Damo, C.P.; Liu, X.; Kung, C.-Y.; Miller, T.A., Implications of the rotationally resolved spectra of the alkoxy radicals for their electronic structure, J. Phys. Chem., 1986, 90, 26, 6766, https://doi.org/10.1021/j100284a011 . [all data]

Bai, Okabe, et al., 1988
Bai, J.; Okabe, H.; Halpern, J.B., Fluorescence spectrum and lifetime of i-C3H7O radical, Chem. Phys. Lett., 1988, 149, 1, 37, https://doi.org/10.1016/0009-2614(88)80344-0 . [all data]

Mund, Fockenberg, et al., 1998
Mund, Ch.; Fockenberg, Ch.; Zellner, R., LIF spectra of n-propoxy and i-propoxy radicals and kinetics of their reactions with O2 and NO2, Ber. Bunsenges. Phys. Chem., 1998, 102, 5, 709, https://doi.org/10.1002/bbpc.19981020502 . [all data]

Carter, Atwell, et al., 2000
Carter, C.C.; Atwell, J.R.; Gopalakrishnan, S.; Miller, T.A., Jet-Cooled Laser-Induced Fluorescence Spectroscopy of Some Alkoxy Radicals, J. Phys. Chem. A, 2000, 104, 40, 9165, https://doi.org/10.1021/jp001835z . [all data]

Jin, Sioutis, et al., 2004
Jin, J.; Sioutis, I.; Tarczay, G.; Gopalakrishnan, S.; Bezant, A.; Miller, T.A., Dispersed fluorescence spectroscopy of primary and secondary alkoxy radicals, J. Chem. Phys., 2004, 121, 23, 11780, https://doi.org/10.1063/1.1814104 . [all data]

Ramond, Davico, et al., 2000, 2
Ramond, T.M.; Davico, G.E.; Schwartz, R.L.; Lineberger, W.C., Vibronic structure of alkoxy radicals via photoelectron spectroscopy, J. Chem. Phys., 2000, 112, 3, 1158, https://doi.org/10.1063/1.480767 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Gopalakrishnan, Zu, et al., 2003
Gopalakrishnan, S.; Zu, L.; Miller, T.A., Radiative and non-radiative decay of selected vibronic levels of the state of alkoxy radicals, Chem. Phys. Lett., 2003, 380, 5-6, 749, https://doi.org/10.1016/j.cplett.2003.08.124 . [all data]

Notes

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• Symbols used in this document:
  

  EA	Electron affinity

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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