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Molybdenum,bis(«eta»5-2,4-cyclopentadien-1-yl)dimethyl-


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas332.5 ± 5.9kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -96.3 ± 2.9 kJ/mol for the enthalpy of formation of Mo(Cp)2(Cl)2(cr)
Deltafgas308.4 ± 7.0kJ/molReviewMartinho SimõesSelected data. The enthalpy of formation relies on -96.3 ± 2.9 kJ/mol for the enthalpy of formation of Mo(Cp)2(Cl)2(cr)

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafsolid262.1 ± 4.2kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -96.3 ± 2.9 kJ/mol for the enthalpy of formation of Mo(Cp)2(Cl)2(cr)
Deltafsolid238.0 ± 5.6kJ/molReviewMartinho SimõesSelected data. The enthalpy of formation relies on -96.3 ± 2.9 kJ/mol for the enthalpy of formation of Mo(Cp)2(Cl)2(cr)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltasub70.4 ± 4.2kJ/molN/APilcher and Skinner, 1983See also Pablo, 2000.; AC
Deltasub70.4 ± 4.2kJ/molRSCCalado, Dias, et al., 1980MS

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C12H16Mo (cr) + 2(Hydrogen chloride bullet 5.55Water) (solution) = C10H10Cl2Mo (cr) + 2Methane (g)

By formula: C12H16Mo (cr) + 2(HCl bullet 5.55H2O) (solution) = C10H10Cl2Mo (cr) + 2CH4 (g)

Quantity Value Units Method Reference Comment
Deltar-193.6 ± 3.0kJ/molRSCCalado, Dias, et al., 1978Please also see Calhorda, Dias, et al., 1987.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Pablo, 2000
Pablo, R.S. De, The vapour pressure of tetrachloroisophthalonitrile by the effusion method, J. Phys. D: Appl. Phys., 2000, 13, 2, 313-319, https://doi.org/10.1088/0022-3727/13/2/028 . [all data]

Calado, Dias, et al., 1980
Calado, J.C.G.; Dias, A.R.; Minas da Piedade M.E.; Martinho Simões, J.A., Rev. Port. Quím., 1980, 22, 57. [all data]

Calado, Dias, et al., 1978
Calado, J.C.G.; Dias, A.R.; Martinho Simões, J.A.; Ribeiro da Silva, M.A.V., J. Chem. Soc., Chem. Commun., 1978, 737.. [all data]

Calhorda, Dias, et al., 1987
Calhorda, M.J.; Dias, A.R.; Minas da Piedade M.E.; Salema, M.S.; Martinho Simões J.A., Organometallics, 1987, 6, 734. [all data]


Notes

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