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Allyl, pentafluoro-, radical


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
B - John E. Bartmess

View reactions leading to C3F5+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
2.99997EIAESauers, Christophorou, et al., 1979From c-C4F8. G3MP2B3 calculations indicate an EA of ca. 1.5 eV, HOF(A-) 42 kcal/mol less stable.; B
2.70 ± 0.20EIAEHarland and Thynne, 1972From cyclo-C4F8; B
2.70 ± 0.10EIAEHarland and Thynne, 1972, 2From CF3CF=CF2; B
2.60 ± 0.40EIAELifshitz and Grajower, 1972From CF3CF=CF2; B
>2.70 ± 0.20EIAEThynne, 1972From CF3CF=CF2; B

Ionization energy determinations

IE (eV) Method Reference Comment
8.44 ± 0.05EIKagramanov, Ujszaszy, et al., 1983LBLHLM

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sauers, Christophorou, et al., 1979
Sauers, I.; Christophorou, J.G.; Carter, J.G., Electron attachment to perfluorocarbon compounds. III. Fragmentation of aliphatic perfluorocarbons of interest to gaseous dielectrics, J. Chem. Phys., 1979, 71, 3016. [all data]

Harland and Thynne, 1972
Harland, P.W.; Thynne, J.C.J., Ionisation of perfluorocyclobutane by electron impact, Int. J. Mass Spectrom. Ion Phys., 1972, 10, 11. [all data]

Harland and Thynne, 1972, 2
Harland, P.W.; Thynne, J.C.J., Dissociative electron capture in perfluoropropylene and perfluoropropane, Int. J. Mass Spectrom. Ion Phys., 1972, 9, 253. [all data]

Lifshitz and Grajower, 1972
Lifshitz, C.; Grajower, R., Dissociative electron capture and dissociative ionization in perfluorocyclobutane, Int. J. Mass Spectrom. Ion Phys., 1972, 10, 25. [all data]

Thynne, 1972
Thynne, J.C.J., Negative Ion Studies with a Time-of-Flight Mass Spectrometer., Dyn. Mass Spectrom., 1972, 3, 67. [all data]

Kagramanov, Ujszaszy, et al., 1983
Kagramanov, N.D.; Ujszaszy, K.; Tamas, J.; Mal'tsev, A.K.; Nefedov, O.M., Mass spectrometric detection of allylic and perfluorallylic free radicals and the determination of their ionization potentials, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1983, 7, 1531, In original 1683. [all data]


Notes

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