Boron fluoride oxide


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 22390.9 ± 0.4 gas C-X 446 447 Mathews, 1966


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 2 BF stretch 875 gas EM Krishnamachari and Vengsarkar
3 BF2 scissors 480.6 gas EM Krishnamachari and Vengsarkar
Mathews and Innes, 1965

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 5220 gas C-A 554 633 Krishnamachari and Vengsarkar
Mathews and Innes, 1965


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 BO stretch 1369 gas EM Krishnamachari and Vengsarkar
2 BF stretch 856.0 gas EM Krishnamachari and Vengsarkar
Mathews and Innes, 1965
3 BF2 scissors 491.0 gas EM Krishnamachari and Vengsarkar
Mathews and Innes, 1965

Additional references: Jacox, 1994, page 200; Dixon, Duxbury, et al., 1967

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mathews, 1966
Mathews, C.W., The 4465-Å emission spectrum of the BOF2 molecule, J. Mol. Spectrosc., 1966, 19, 1-4, 203, https://doi.org/10.1016/0022-2852(66)90242-6 . [all data]

Krishnamachari and Vengsarkar
Krishnamachari, S.L.N.G.; Vengsarkar, B.R., Proc. C. S. I. R. Sympos. Banaras, 1963, p. 87. [all data]

Mathews and Innes, 1965
Mathews, C.W.; Innes, K.K., The emission spectrum of the BOF2 molecule, J. Mol. Spectrosc., 1965, 15, 2, 199, https://doi.org/10.1016/0022-2852(65)90036-6 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Dixon, Duxbury, et al., 1967
Dixon, R.N.; Duxbury, G.; Mitchell, R.C.; Simons, J.P., The Ultraviolet Absorption Spectrum of the FFormulaCN Radical, Proc. Roy. Soc. (London) A300, 1967, 300, 1462, 405, https://doi.org/10.1098/rspa.1967.0178 . [all data]


Notes

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