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Salicylic acid, 2TMS derivative


Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillarySE-30180.1508.Shakirov, Tsypysheva, et al., 1988Column length: 20. m; Column diameter: 0.2 mm

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryVF-5MS1525.Todua, 201130. m/0.25 mm/0.25 «mu»m, He; Tstart: 60. C; Tend: 270. C
CapillaryDB-51524.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryDB-51524.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryDB-51525.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryDB-51525.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ht1519.Jaroszynska and Ligor, 200530. m/0.25 mm/0.1 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ht1519.Jaroszynska and Ligor, 200530. m/0.25 mm/0.1 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ht1520.Jaroszynska and Ligor, 200530. m/0.25 mm/0.1 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ht1521.Jaroszynska and Ligor, 200530. m/0.25 mm/0.1 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ms1507.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ms1507.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryDB-5MS1508.3Jonsson, Johansson, et al., 200510. m/0.18 mm/0.18 «mu»m, 70. C @ 2. min, 40. K/min, 320. C @ 2. min
CapillaryDB-51519.Jaroszynska, 200330. m/0.25 mm/0.25 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 240. C
CapillaryDB-51525.Jaroszynska, 200330. m/0.25 mm/0.25 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 240. C
CapillaryDB-51522.Jaroszynska, 200330. m/0.25 mm/0.25 «mu»m, He, 7. K/min; Tstart: 50. C; Tend: 240. C
CapillaryDB-51528.Jaroszynska, 200330. m/0.25 mm/0.25 «mu»m, He, 7. K/min; Tstart: 50. C; Tend: 240. C
CapillarySE-521524.Lefevere, Verhaeghe, et al., 198925. m/0.32 mm/0.52 «mu»m, He, 5. K/min; Tstart: 70. C; Tend: 270. C
CapillaryCP Sil 5 CB1505.Wurth, Kumps, et al., 1989N2, 60. C @ 0.5 min, 6. K/min, 280. C @ 5. min
CapillarySE-521522.Lefevere, Verhaeghe, et al., 198825. m/0.20 mm/0.40 «mu»m, He, 5. K/min; Tstart: 50. C; Tend: 270. C
PackedOV-11505.Tanaka, Hine, et al., 1980N2, 100-120 mesh, 70. C @ 0.5 min, 28. K/min; Column length: 1.8 m; Tend: 290. C
PackedOV-11502.Mattsson and Petersson, 1977N2, Supelcoport, 4. K/min; Column length: 2. m; Tstart: 80. C; Tend: 240. C
PackedOV-11510.Butts, 1972He, Chromosorb W HP (80-100 mesh), 10. K/min; Column length: 2. m; Tstart: 100. C; Tend: 325. C

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryDB-11507.Tsai, Oliphant, et al., 1985He; Program: not specified
PackedOV-1011505.Tanaka and Hine, 1982Program: not specified

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryHP-51524.Isidorov, Kotowska, et al., 200530. m/0.25 mm/0.25 «mu»m, He; Tstart: 50. C; Tend: 300. C
CapillaryHP-51522.Isidorov, Kotowska, et al., 200530. m/0.25 mm/0.25 «mu»m, He, 5. K/min; Tstart: 50. C; Tend: 300. C

References

Go To: Top, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Shakirov, Tsypysheva, et al., 1988
Shakirov, L.G.; Tsypysheva, L.G.; Suleimamova, R.A.; Naimushin, A.I.; Tsypyshev, O.Yu., Gas chromatographic determination of the products of the synthesis of chlorine-substituted salicylic acids, Zh. Anal. Khim., 1988, 43, 143-146. [all data]

Todua, 2011
Todua, N.G., Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2011. [all data]

Jaroszynska and Ligor, 2005
Jaroszynska, J.; Ligor, T., The identification of phenolic compounds by a gas chromatographic method on three capillary columns with the same non-polar stationary phase, Anal. Chim. Acta., 2005, 539, 1-2, 11-15, https://doi.org/10.1016/j.aca.2005.03.024 . [all data]

Jonsson, Johansson, et al., 2005
Jonsson, P.; Johansson, A.I.; Gullberg, J.; Trygg, J.; Jiye, A.; Grung, B.; Marklund, S.; Sjöström, M.; Antti, H.; Moritz, T., High-throughput data analysis for detecting and identifying differences between samples in GC/MS-based metabolomic analyses, Anal. Chem., 2005, 77, 17, 5635-5642, https://doi.org/10.1021/ac050601e . [all data]

Jaroszynska, 2003
Jaroszynska, J., Isolation of free phenolic compounds from arboreal leaves by use of the Florisil/C18 system, Anal. Bioanal. Chem., 2003, 377, 4, 702-708, https://doi.org/10.1007/s00216-003-2155-z . [all data]

Lefevere, Verhaeghe, et al., 1989
Lefevere, M.F.; Verhaeghe, B.J.; Declerck, D.H.; Van Bocxlaer, J.F.; De Leenheer, A.P.; De Sagher, R.M., Metabolic Profiling of Urinary Organic Acids by Single and Multicolumn Capillary Gas Chromatography, J. Chromatogr. Sci., 1989, 27, 1, 23-29, https://doi.org/10.1093/chromsci/27.1.23 . [all data]

Wurth, Kumps, et al., 1989
Wurth, C.; Kumps, A.; Mardens, Y., Urinary organic acids: Retention indices on two capillary gas chromatography columns, J. Chromatogr., 1989, 491, 186-192, https://doi.org/10.1016/S0378-4347(00)82831-5 . [all data]

Lefevere, Verhaeghe, et al., 1988
Lefevere, M.F.; Verhaeghe, B.J.; Declerck, D.M.; de Leenheer, A.P., Automated profiling of urinary organic acids by dual-column gas chromatography and gas chromatography/mass spectrometry, Biomed. Environ. Mass Spectrom., 1988, 15, 6, 311-322, https://doi.org/10.1002/bms.1200150603 . [all data]

Tanaka, Hine, et al., 1980
Tanaka, K.; Hine, D.G.; West-Dull, A.; Lynn, T.B., Gas-chromatographic method of analysis for urinary organic acids. I. Retention indices of 155 metabolically important compounds, Clin. Chem., 1980, 26, 13, 1839-1846. [all data]

Mattsson and Petersson, 1977
Mattsson, M.; Petersson, G., Reference GLC Data for the Analysis of Phenolic Compounds as Trimethylsilyl Derivatives, J. Chromatogr. Sci., 1977, 15, 12, 546-554, https://doi.org/10.1093/chromsci/15.12.546 . [all data]

Butts, 1972
Butts, W.C., Two-Column Gas Chromatography of Trimethylsilyl Derivatives of Biochemically Significant Compounds, Anal. Biochemistry, 1972, 46, 1, 187-199, https://doi.org/10.1016/0003-2697(72)90411-3 . [all data]

Tsai, Oliphant, et al., 1985
Tsai, M.Y.; Oliphant, C.; Josephson, M.W., Identification of Metabolites Diagnostic for Organic Acidurias by Simultaneous Dual-Column Capillary Gas Chromatography, J. Chromatogr., 1985, 341, 1-10, https://doi.org/10.1016/S0378-4347(00)84004-9 . [all data]

Tanaka and Hine, 1982
Tanaka, K.; Hine, D.G., Compilation of Gas Chromatographic Retention Indices of 163 Metabolically Important Organic Acids, and Their Use in Detection of Patients with Organic Acidurias, J. Chromatogr., 1982, 239, 301-322, https://doi.org/10.1016/S0021-9673(00)81990-1 . [all data]

Isidorov, Kotowska, et al., 2005
Isidorov, V.A.; Kotowska, U.; Vinogorova, V.T., GC Identification of organic compounds based on partition coefficients of their TMS derivatives in a hexane-acetonitrile system and retention indices, Anal. Sci., 2005, 21, 12, 1483-1489, https://doi.org/10.2116/analsci.21.1483 . [all data]


Notes

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