Salicylic acid, 2TMS derivative


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 2010
NIST MS number 374323

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Gas Chromatography

Go To: Top, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillarySE-30180.1508.Shakirov, Tsypysheva, et al., 1988Column length: 20. m; Column diameter: 0.2 mm

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryVF-5MS1525.Todua, 201130. m/0.25 mm/0.25 μm, He; Tstart: 60. C; Tend: 270. C
CapillaryDB-51524.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryDB-51524.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryDB-51525.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryDB-51525.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ht1519.Jaroszynska and Ligor, 200530. m/0.25 mm/0.1 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ht1519.Jaroszynska and Ligor, 200530. m/0.25 mm/0.1 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ht1520.Jaroszynska and Ligor, 200530. m/0.25 mm/0.1 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ht1521.Jaroszynska and Ligor, 200530. m/0.25 mm/0.1 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ms1507.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ms1507.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryDB-5MS1508.3Jonsson, Johansson, et al., 200510. m/0.18 mm/0.18 μm, 70. C @ 2. min, 40. K/min, 320. C @ 2. min
CapillaryDB-51519.Jaroszynska, 200330. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 240. C
CapillaryDB-51525.Jaroszynska, 200330. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 240. C
CapillaryDB-51522.Jaroszynska, 200330. m/0.25 mm/0.25 μm, He, 7. K/min; Tstart: 50. C; Tend: 240. C
CapillaryDB-51528.Jaroszynska, 200330. m/0.25 mm/0.25 μm, He, 7. K/min; Tstart: 50. C; Tend: 240. C
CapillarySE-521524.Lefevere, Verhaeghe, et al., 198925. m/0.32 mm/0.52 μm, He, 5. K/min; Tstart: 70. C; Tend: 270. C
CapillaryCP Sil 5 CB1505.Wurth, Kumps, et al., 1989N2, 60. C @ 0.5 min, 6. K/min, 280. C @ 5. min
CapillarySE-521522.Lefevere, Verhaeghe, et al., 198825. m/0.20 mm/0.40 μm, He, 5. K/min; Tstart: 50. C; Tend: 270. C
PackedOV-11505.Tanaka, Hine, et al., 1980N2, 100-120 mesh, 70. C @ 0.5 min, 28. K/min; Column length: 1.8 m; Tend: 290. C
PackedOV-11502.Mattsson and Petersson, 1977N2, Supelcoport, 4. K/min; Column length: 2. m; Tstart: 80. C; Tend: 240. C
PackedOV-11510.Butts, 1972He, Chromosorb W HP (80-100 mesh), 10. K/min; Column length: 2. m; Tstart: 100. C; Tend: 325. C

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryDB-11507.Tsai, Oliphant, et al., 1985He; Program: not specified
PackedOV-1011505.Tanaka and Hine, 1982Program: not specified

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryHP-51524.Isidorov, Kotowska, et al., 200530. m/0.25 mm/0.25 μm, He; Tstart: 50. C; Tend: 300. C
CapillaryHP-51522.Isidorov, Kotowska, et al., 200530. m/0.25 mm/0.25 μm, He, 5. K/min; Tstart: 50. C; Tend: 300. C

References

Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Shakirov, Tsypysheva, et al., 1988
Shakirov, L.G.; Tsypysheva, L.G.; Suleimamova, R.A.; Naimushin, A.I.; Tsypyshev, O.Yu., Gas chromatographic determination of the products of the synthesis of chlorine-substituted salicylic acids, Zh. Anal. Khim., 1988, 43, 143-146. [all data]

Todua, 2011
Todua, N.G., Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2011. [all data]

Jaroszynska and Ligor, 2005
Jaroszynska, J.; Ligor, T., The identification of phenolic compounds by a gas chromatographic method on three capillary columns with the same non-polar stationary phase, Anal. Chim. Acta., 2005, 539, 1-2, 11-15, https://doi.org/10.1016/j.aca.2005.03.024 . [all data]

Jonsson, Johansson, et al., 2005
Jonsson, P.; Johansson, A.I.; Gullberg, J.; Trygg, J.; Jiye, A.; Grung, B.; Marklund, S.; Sjöström, M.; Antti, H.; Moritz, T., High-throughput data analysis for detecting and identifying differences between samples in GC/MS-based metabolomic analyses, Anal. Chem., 2005, 77, 17, 5635-5642, https://doi.org/10.1021/ac050601e . [all data]

Jaroszynska, 2003
Jaroszynska, J., Isolation of free phenolic compounds from arboreal leaves by use of the Florisil/C18 system, Anal. Bioanal. Chem., 2003, 377, 4, 702-708, https://doi.org/10.1007/s00216-003-2155-z . [all data]

Lefevere, Verhaeghe, et al., 1989
Lefevere, M.F.; Verhaeghe, B.J.; Declerck, D.H.; Van Bocxlaer, J.F.; De Leenheer, A.P.; De Sagher, R.M., Metabolic Profiling of Urinary Organic Acids by Single and Multicolumn Capillary Gas Chromatography, J. Chromatogr. Sci., 1989, 27, 1, 23-29, https://doi.org/10.1093/chromsci/27.1.23 . [all data]

Wurth, Kumps, et al., 1989
Wurth, C.; Kumps, A.; Mardens, Y., Urinary organic acids: Retention indices on two capillary gas chromatography columns, J. Chromatogr., 1989, 491, 186-192, https://doi.org/10.1016/S0378-4347(00)82831-5 . [all data]

Lefevere, Verhaeghe, et al., 1988
Lefevere, M.F.; Verhaeghe, B.J.; Declerck, D.M.; de Leenheer, A.P., Automated profiling of urinary organic acids by dual-column gas chromatography and gas chromatography/mass spectrometry, Biomed. Environ. Mass Spectrom., 1988, 15, 6, 311-322, https://doi.org/10.1002/bms.1200150603 . [all data]

Tanaka, Hine, et al., 1980
Tanaka, K.; Hine, D.G.; West-Dull, A.; Lynn, T.B., Gas-chromatographic method of analysis for urinary organic acids. I. Retention indices of 155 metabolically important compounds, Clin. Chem., 1980, 26, 13, 1839-1846. [all data]

Mattsson and Petersson, 1977
Mattsson, M.; Petersson, G., Reference GLC Data for the Analysis of Phenolic Compounds as Trimethylsilyl Derivatives, J. Chromatogr. Sci., 1977, 15, 12, 546-554, https://doi.org/10.1093/chromsci/15.12.546 . [all data]

Butts, 1972
Butts, W.C., Two-Column Gas Chromatography of Trimethylsilyl Derivatives of Biochemically Significant Compounds, Anal. Biochemistry, 1972, 46, 1, 187-199, https://doi.org/10.1016/0003-2697(72)90411-3 . [all data]

Tsai, Oliphant, et al., 1985
Tsai, M.Y.; Oliphant, C.; Josephson, M.W., Identification of Metabolites Diagnostic for Organic Acidurias by Simultaneous Dual-Column Capillary Gas Chromatography, J. Chromatogr., 1985, 341, 1-10, https://doi.org/10.1016/S0378-4347(00)84004-9 . [all data]

Tanaka and Hine, 1982
Tanaka, K.; Hine, D.G., Compilation of Gas Chromatographic Retention Indices of 163 Metabolically Important Organic Acids, and Their Use in Detection of Patients with Organic Acidurias, J. Chromatogr., 1982, 239, 301-322, https://doi.org/10.1016/S0021-9673(00)81990-1 . [all data]

Isidorov, Kotowska, et al., 2005
Isidorov, V.A.; Kotowska, U.; Vinogorova, V.T., GC Identification of organic compounds based on partition coefficients of their TMS derivatives in a hexane-acetonitrile system and retention indices, Anal. Sci., 2005, 21, 12, 1483-1489, https://doi.org/10.2116/analsci.21.1483 . [all data]


Notes

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