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trifluoromethyl hypofluorite


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil178.KN/APCR Inc., 1990BS

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
3.70179.AStephenson and Malanowski, 1987The table in Ref. Kellogg and Cady, 1948 gives the temperatures in °C; however, all of the equations and graphs in the article suggest that the temperature should be in Kelvin. We have assumed that the tabulated temperatures are in Kelvin; the results closely correspond to the entry in Ref. Stephenson and Malanowski, 1987.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
417.9 - 467.14.00665630.837-293.801Kellogg and Cady, 1948Coefficents calculated by NIST from author's data.

References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Kellogg and Cady, 1948
Kellogg, K.B.; Cady, George H., Trifluoromethyl Hypofluorite, J. Am. Chem. Soc., 1948, 70, 12, 3986-3990, https://doi.org/10.1021/ja01192a006 . [all data]


Notes

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