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Silane, trifluoromethyl-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
12.48 ± 0.04PIMurphy and Beauchamp, 1977LLK
13.2PERoberge, Sandorfy, et al., 1978Vertical value; LLK
13.24 ± 0.02PECradock, Ebsworth, et al., 1973Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
F3Si+13.33 ± 0.05CH3PIMurphy and Beauchamp, 1977LLK

De-protonation reactions

CH2F3Si- + Hydrogen cation = Silane, trifluoromethyl-

By formula: CH2F3Si- + H+ = CH3F3Si

Quantity Value Units Method Reference Comment
Deltar1542. ± 16.kJ/molG+TSAllison and McMahon, 1990gas phase; Between acetone and acetaldehyde. In conflict with Campanaro, Marvin, et al., 1988; B
Deltar1555. ± 19.kJ/molG+TSCampanaro, Marvin, et al., 1988gas phase; Between HF and acetone; B
Quantity Value Units Method Reference Comment
Deltar1508. ± 16.kJ/molIMRBAllison and McMahon, 1990gas phase; Between acetone and acetaldehyde. In conflict with Campanaro, Marvin, et al., 1988; B
Deltar1522. ± 19.kJ/molIMRBCampanaro, Marvin, et al., 1988gas phase; Between HF and acetone; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Murphy and Beauchamp, 1977
Murphy, M.K.; Beauchamp, J.L., Photoionization mass spectrometry of the fluoromethylsilanes (CH3)n F4-nSi (n = 1-4), J. Am. Chem. Soc., 1977, 99, 2085. [all data]

Roberge, Sandorfy, et al., 1978
Roberge, R.; Sandorfy, C.; Matthews, J.I.; Strausz, O.P., The far ultraviolet HeI photoelectron spectra of alkyl and fluorine substituted silane derivatives, J. Chem. Phys., 1978, 69, 5105. [all data]

Cradock, Ebsworth, et al., 1973
Cradock, S.; Ebsworth, E.A.V.; Whiteford, R.A., Photoelectron spectra of some simple fluorosilanes, J. Chem. Soc. Dalton Trans., 1973, 22, 2401. [all data]

Allison and McMahon, 1990
Allison, C.E.; McMahon, T.B., How Strong is the Si=C Bond in Fluoro- and Methyl Substituted Silaethylenes? An Experimental Determination of Pi Bond Strengths, J. Am. Chem. Soc., 1990, 112, 5, 1672, https://doi.org/10.1021/ja00161a002 . [all data]

Campanaro, Marvin, et al., 1988
Campanaro, A.; Marvin, C.H.; Morehouse, S.P.; McMahon, T.B., A Gas-phase Anionic Analog of the Wittig Reaction. An Ion Cyclotron Resonance Study of the Gas Phase Ion Chemistry of Silyl Carbanions., Org. Mass Spectrom., 1988, 23, 9, 663, https://doi.org/10.1002/oms.1210230907 . [all data]


Notes

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