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Borane, difluoromethyl-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
12.54 ± 0.03EISteele, Nichols, et al., 1962RDSH
13.16PEBerger, Kroner, et al., 1976Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
BF2+13.62 ± 0.02CH3EISteele, Nichols, et al., 1962RDSH
CH2+16.9 ± 0.1?EISteele, Nichols, et al., 1962RDSH
CH2BF+13.38 ± 0.02?EISteele, Nichols, et al., 1962RDSH
CH3+14.8 ± 0.1?EISteele, Nichols, et al., 1962RDSH
CH3BF+15.1 ± 0.1FEISteele, Nichols, et al., 1962RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Steele, Nichols, et al., 1962
Steele, W.C.; Nichols, L.D.; Stone, F.G.A., An electron impact investigation of some organoboron difluorides, J. Am. Chem. Soc., 1962, 84, 1154. [all data]

Berger, Kroner, et al., 1976
Berger, H.-O.; Kroner, J.; Noth, H., Die borhalogen-bindung in Methylhalogenboranen: Photoelektronenspektren und ab initio-Rechnungen, Chem. Ber., 1976, 109, 2266. [all data]


Notes

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