Phosphorodiamidothioic chloride, tetramethyl-
- Formula: C4H12ClN2PS
- Molecular weight: 186.643
- IUPAC Standard InChIKey: CDAZTLZRVPHQHS-UHFFFAOYSA-N
- CAS Registry Number: 3732-81-8
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Tetramethyldiamidothiophosphoryl chloride; Tetramethylphosphorodiamidothioic chloride; Bis(dimethylamino)phosphinothioic chloride; N,N,N',N'-Tetramethylphosphorodiamidothioic chloride; Bis(dimethylamino)chlorophosphine sulfide
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Phase change data
Go To: Top, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Robert L. Brown and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 295. | K | N/A | Buckingham and Donaghy, 1982 |
Reduced pressure boiling point
Tboil (K) | Pressure (bar) | Reference |
---|---|---|
330. to 331. | 0.001 | Buckingham and Donaghy, 1982 |
Gas phase ion energetics data
Go To: Top, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.23 ± 0.02 | PE | Vilesov, Lopatin, et al., 1974 | |
8.23 ± 0.003 | PE | Vovna, Lopatin, et al., 1973 | |
8.75 | PE | Zverev, Vilesov, et al., 1975 | Vertical value |
IR Spectrum
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Coblentz Society, Inc.
Spectrum
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Additional Data
View scan of original (hardcopy) spectrum.
Owner | COBLENTZ SOCIETY Collection (C) 2018 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Source reference | COBLENTZ NO. 3196 |
Date | Not specified, most likely prior to 1970 |
Instrument | Not specified, most likely a prism, grating, or hybrid spectrometer. |
Data processing | (NO SPECTRUM, ONLY SCANNED IMAGE IS AVAILABLE) |
Mass spectrum (electron ionization)
Go To: Top, Phase change data, Gas phase ion energetics data, IR Spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | R.C. DOUGHERTY |
NIST MS number | 36890 |
References
Go To: Top, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M.,
Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]
Vilesov, Lopatin, et al., 1974
Vilesov, F.I.; Lopatin, S.N.; Vovna, V.I.; Paetzold, R.; Niendorf, K.,
Untersuchungen an molekulkomplexen. 3. Mitteilung: Zusammenhang zwischen der ionisierungsenergie von R1R2R3PS-molekulen und der stabilitat ihrer molekulkomplexe mit jod,
Z. Phys. Chem. (Leipzig), 1974, 255, 661. [all data]
Vovna, Lopatin, et al., 1973
Vovna, V.I.; Lopatin, S.N.; Pettsold, R.; Vilesov, F.I.; Akopyan, M.E.,
Photoelectron spectra of thiophosphorylchloride and some of its aminosubstituted derivatives,
Opt. Spectrosc., 1973, 34, 501, In original 868. [all data]
Zverev, Vilesov, et al., 1975
Zverev, V.V.; Vilesov, F.I.; Vovna, V.I.; Lopatin, S.N.; Kitaev, Y.P.,
Photoelectron spectra,
Izv. Akad. Nauk SSSR, Ser. Khim., 1975, 1975, 1051. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References
- Symbols used in this document:
Tboil Boiling point Tfus Fusion (melting) point - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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