Antimony trimer


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

View reactions leading to Sb3+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
1.850 ± 0.030LPESPolak, Gerber, et al., 1992Vertical Detachment Energy: 1.85±0.03 eV.; B

Ionization energy determinations

IE (eV) Method Reference Comment
9.0 ± 0.2EIKordis and Gingerich, 1973LLK
7.50 ± 0.13EICabaud, Hoareau, et al., 1973LLK

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   a


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Tx = 11300 T gas Polak, Gerber, et al., 1992

Additional references: Jacox, 1994, page 82

Notes

TTentative assignment or approximate value
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Polak, Gerber, et al., 1992
Polak, M.L.; Gerber, G.; Ho, J.; Lineberger, W.C., Photoelectron Spectroscopy of Small Antimony Cluster Anions - Sb(-) Sb2(-), Sb3(-), and Sb4(-), J. Chem. Phys., 1992, 97, 12, 8990, https://doi.org/10.1063/1.463326 . [all data]

Kordis and Gingerich, 1973
Kordis, J.; Gingerich, K.A., Mass spectroscopic investigation of the equilibrium dissociation of gaseous Sb2, Sb3, Sb4, SbP, SbP3, and P2, J. Chem. Phys., 1973, 58, 5141. [all data]

Cabaud, Hoareau, et al., 1973
Cabaud, B.; Hoareau, A.; Nounou, P.; Uzan, R., High temperature mass spectrometric study of polyatomic antimony species by electron impact. Direct evidence for the existence of Sb3 molecules, Int. J. Mass Spectrom. Ion Phys., 1973, 11, 157. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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