1,3,6-Cyclooctatriene

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas46.92kcal/molEqkGreathead and Orchard, 1983 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

3Hydrogen + 1,3,6-Cyclooctatriene = Cyclooctane

By formula: 3H2 + C8H10 = C8H16

Quantity Value Units Method Reference Comment
Δr-79.91 ± 0.17kcal/molChydTurner, Mallon, et al., 1973liquid phase; solvent: Glacial acetic acid

1,3,6-Cyclooctatriene = 1,3,5-Cyclooctatriene

By formula: C8H10 = C8H10

Quantity Value Units Method Reference Comment
Δr-3.25 ± 0.05kcal/molEqkGreathead and Orchard, 1983gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Greathead and Orchard, 1983
Greathead, J.M.; Orchard, S.W., Kinetic and equilibrium study of gas-phase interconversions of 1,3,6-cyclooctatriene, 1,3,5-cyclooctatriene and bicyclo[4.2.0]octa-2,4-diene, Int. J. Chem. Kinet., 1983, 15, 1069-1080. [all data]

Turner, Mallon, et al., 1973
Turner, R.B.; Mallon, B.J.; Tichy, M.; Doering, W.v.E.; Roth, W.R.; Schroder, G., Heats of hydrogenation. X. Conjugative interaction in cyclic dienes and trienes, J. Am. Chem. Soc., 1973, 95, 8605-8610. [all data]


Notes

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