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Acetic acid, cyano-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

C3H2NO2- + Hydrogen cation = Acetic acid, cyano-

By formula: C3H2NO2- + H+ = C3H3NO2

Quantity Value Units Method Reference Comment
Deltar1382. ± 8.8kJ/molG+TSTaft and Topsom, 1987gas phase; B
Quantity Value Units Method Reference Comment
Deltar1354. ± 8.4kJ/molIMRETaft and Topsom, 1987gas phase; B

Acetic acid, cyano-, methyl ester + Water = Acetic acid, cyano- + Methyl Alcohol

By formula: C4H5NO2 + H2O = C3H3NO2 + CH4O

Quantity Value Units Method Reference Comment
Deltar-54. ± 2.kJ/molEqkGuthrie and Cullimore, 1980liquid phase; ALS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Taft and Topsom, 1987
Taft, R.W.; Topsom, R.D., The Nature and Analysis of Substituent Effects, Prog. Phys. Org. Chem., 1987, 16, 1. [all data]

Guthrie and Cullimore, 1980
Guthrie, J.P.; Cullimore, P.A., Effect of the acyl substituent on the equilibrium constant for hydration of esters, Can. J. Chem., 1980, 58, 1281-1294. [all data]


Notes

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