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2,4-Dimethylfuran

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Phase change data

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director

Quantity Value Units Method Reference Comment
Tboil367.15KN/AScharf and Walters, 1978Uncertainty assigned by TRC = 2. K
Tboil368.65KN/ASchreurs, de Jong, et al., 1976Uncertainty assigned by TRC = 2. K
Tboil368.25KN/AGalesloot, Brandsma, et al., 1969Uncertainty assigned by TRC = 0.6 K
Tboil367.9KN/AMorel and Verkade, 1951Uncertainty assigned by TRC = 0.5 K

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

View reactions leading to C6H8O+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
Proton affinity (review)894.7kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity862.3kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
8.39 ± 0.10EIGrutzmacher and Spilker, 1985LBLHLM

Mass spectrum (electron ionization)

Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin TNO Volatile Compounds in Food - Chemical Concepts
NIST MS number 249758

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Scharf and Walters, 1978
Scharf, H.-D.; Walters, E., A New Synthesis Principle for Furane Derivatives II. Fragmentation and Recycling Condensation of 1,3-Dioxolane-4-ylium Ions, Chem. Ber., 1978, 111, 639. [all data]

Schreurs, de Jong, et al., 1976
Schreurs, P.H.; de Jong, A.J.; Brandsma, L., Recl. Trav. Chim. Pays-Bas, 1976, 95, 75. [all data]

Galesloot, Brandsma, et al., 1969
Galesloot, W.G.; Brandsma, L.; Arens, J.F., Formation of Substituted Furans from Alcohols with A Conjugated Enzyme System, Recl. Trav. Chim. Pays-Bas, 1969, 88, 671. [all data]

Morel and Verkade, 1951
Morel, Th.; Verkade, P.E., A New Method for Synthesis of Furan Derivatives III., Recl. Trav. Chim. Pays-Bas, 1951, 70, 35. [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Grutzmacher and Spilker, 1985
Grutzmacher, H.-F.; Spilker, R., Loss of CO from 4,6-dimethyl-2-pyrone and 2,6-dimethyl-4-pyrone radical cations, Org. Mass Spectrom., 1985, 20, 258. [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References