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1-Hexadecanol

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DH - Eugene S. Domalski and Elizabeth D. Hearing
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafsolid-686.4 ± 0.4kJ/molCcbMosselman and Dekker, 1975ALS
Deltafsolid-687.1 ± 2.0kJ/molCcbGundry, Harrop, et al., 1969ALS
Deltafsolid-683.3 ± 3.8kJ/molCcbParks, Mosley, et al., 1950Reanalyzed by Cox and Pilcher, 1970, Original value = -684.29 kJ/mol; see Richardson and Parks, 1939; ALS
Quantity Value Units Method Reference Comment
Deltacsolid-10510. ± 8.kJ/molCcbFreeman and Bagby, 1989Corresponding «DELTA»fsolid = -644. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-10468.9 ± 0.7kJ/molCcbMosselman and Dekker, 1975Corresponding «DELTA»fsolid = -686.4 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-10486.3 ± 1.7kJ/molCcbGundry, Harrop, et al., 1969Corresponding «DELTA»fsolid = -669.01 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-10471.9 ± 3.8kJ/molCcbParks, Mosley, et al., 1950Reanalyzed by Cox and Pilcher, 1970, Original value = -10471.2 kJ/mol; see Richardson and Parks, 1939; Corresponding «DELTA»fsolid = -683.33 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar451.9J/mol*KN/AParks, Kennedy, et al., 1956Extrapolation below 80 K, 115.3 J/mol*K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
618.2333.15Khasanshin and Zykova, 1989T = 333 to 583 K.; DH
524.323.Mosselman, Mourik, et al., 1974T = 323 to 346 K.; DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
422.298.15Mosselman, Mourik, et al., 1974T = 293 to 311 K.; DH
441.24290.Parks, Kennedy, et al., 1956T = 80 to 290 K.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mosselman and Dekker, 1975
Mosselman, C.; Dekker, H., Enthalpies of formation of n-alkan-1-ols, J. Chem. Soc. Faraday Trans. 1, 1975, 417-424. [all data]

Gundry, Harrop, et al., 1969
Gundry, H.A.; Harrop, D.; Head, A.J.; Lewis, G.B., Thermodynamic properties of organic oxygen compounds. 21. Enthalpies of combustion of benzoic acid, pentan-1-ol, octan-1-ol, and hexadecan-1-ol, J. Chem. Thermodyn., 1969, 1, 321-332. [all data]

Parks, Mosley, et al., 1950
Parks, G.S.; Mosley, J.R.; Peterson, P.V., Jr., Heats of combustion and formation of some organic compounds containing oxygen, J. Chem. Phys., 1950, 18, 152. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Richardson and Parks, 1939
Richardson, J.W.; Parks, G.S., Thermal data on organic compounds. XIX. Modern combustion data for some non-volatile compounds containing carbon, hydrogen and oxygen, J. Am. Chem. Soc., 1939, 61, 3543-3546. [all data]

Freeman and Bagby, 1989
Freeman, B.; Bagby, M.O., Heats of combustion of fatty esters and triglycerides, J. Am. Oil Chem. Soc., 1989, 66, 1601-1605. [all data]

Parks, Kennedy, et al., 1956
Parks, G.S.; Kennedy, W.D.; Gates, R.R.; Mosley, J.R.; Moore, G.E.; Renquist, M.L., Thermal data on organic compounds. XXVI. Some heat capacity, entropy and free energy data for seven compounds containing oxygen., Not In System, 1956, 78, 56-59. [all data]

Khasanshin and Zykova, 1989
Khasanshin, T.S.; Zykova, T.B., Specific heat of saturated monatomic alcohols, Inzh. -Fiz. Zhur., 1989, 56(6), 991-994. [all data]

Mosselman, Mourik, et al., 1974
Mosselman, C.; Mourik, J.; Dekker, H., Enthalpies of phase change and heat capacities of some long-chain alcohols. Adiabatic semi-microcalorimeter for studies of polymorphism, J. Chem. Thermodynam., 1974, 6, 477-487. [all data]


Notes

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