2,2'-Bipyridine

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil546.7KN/AWeast and Grasselli, 1989BS
Tboil545.6KN/ABuckingham and Donaghy, 1982BS
Quantity Value Units Method Reference Comment
Tfus342.6KN/ABuckingham and Donaghy, 1982BS
Quantity Value Units Method Reference Comment
Ttriple343.05KN/ASevastyanova, Suvorov, et al., 1990Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Δvap67.0 ± 2.3kJ/molCGCLipkind and Chickos, 2009See also Lipkind, Hanshaw, et al., 2009.; AC
Quantity Value Units Method Reference Comment
Δsub75.0 ± 5.0kJ/molBEmmenegger, 1996AC
Δsub81.8 ± 2.3kJ/molCRibeiro da Silva, Morais, et al., 1995ALS
Δsub81.8kJ/molN/ARibeiro da Silva, Morais, et al., 1995DRB
Δsub81.8 ± 2.3kJ/molCRibeiro da Silva, Morais, et al., 1995AC
Δsub81.9kJ/molN/AFaour and Akasheh, 1985DRB

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
20.4345.DSCLipkind, Hanshaw, et al., 2009AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]

Sevastyanova, Suvorov, et al., 1990
Sevastyanova, T.N.; Suvorov, V.; Konysheva, I.I., Thermodynamics of vaporisation of 2,2'-bipyridine and some binary systems with it in Vses. Konf. Term. Org. Soedin. 6th, Minsk, p 33, 1990. [all data]

Lipkind and Chickos, 2009
Lipkind, D.; Chickos, J.S., , Abstract from 38th Great Lakes Regional Meeting of the American Chemical Society, May 13-16, Chicago, IL, 2009, GLRM-275. [all data]

Lipkind, Hanshaw, et al., 2009
Lipkind, Dmitri; Hanshaw, William; Chickos, James S., Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Heterocycles and Related Compounds, J. Chem. Eng. Data, 2009, 54, 10, 2930-2943, https://doi.org/10.1021/je900034d . [all data]

Emmenegger, 1996
Emmenegger, Franzpeter, The Complex of Co(2,2,6,6-tetramethyl-3,5-heptanedionate) 2 with 2,2'-Bipyridine. Its Formation in the Gas Phase and in Solution, Inorg. Chem., 1996, 35, 20, 5931-5934, https://doi.org/10.1021/ic9605130 . [all data]

Ribeiro da Silva, Morais, et al., 1995
Ribeiro da Silva, M.A.V.; Morais, V.M.F.; Matos, M.A.R.; Rio, C.M.A., Thermochemical and theoretical studies of some bipyridines, J. Org. Chem., 1995, 60, 5291-5294. [all data]

Faour and Akasheh, 1985
Faour, M.; Akasheh, T.S., Heat of combustion of some N-heterocycle compounds. Part 1, J. Chem. Soc. Perkin Trans. 2, 1985, 811-713. [all data]


Notes

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