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Dimolybdenum tetrakis(trifluoroacetate)


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Deltasub27.15 ± 0.41kcal/molN/ACarson, 1984MS

Enthalpy of sublimation

DeltasubH (kcal/mol) Temperature (K) Method Reference Comment
27.15 ± 0.41350.ME,TECarson, 1984, 2Based on data from 330. - 370. K.; AC

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
8.07PEBancroft, Pellach, et al., 1982LBLHLM
8.76PEBancroft, Pellach, et al., 1982Vertical value; LBLHLM
8.67 ± 0.05PEColeman, Green, et al., 1979Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Carson, 1984
Carson, A.S., J. Chem. Thermodyn., 1984, 16, 427. [all data]

Carson, 1984, 2
Carson, A.S., The molar enthalpy of dehydration of Cr2(O2CCH3)4·2H2O(cr) and the molar enthalpies of sublimation of Cr2(O2CCH3)4(cr), Mo2(O2CCH3)4(cr), and Mo2(O2CCF3)4(cr), The Journal of Chemical Thermodynamics, 1984, 16, 5, 427-429, https://doi.org/10.1016/0021-9614(84)90198-8 . [all data]

Bancroft, Pellach, et al., 1982
Bancroft, G.M.; Pellach, E.; Sattelberger, A.P.; McLaughlin, K.W., The photoelectron spectrum of quadruply bonded W2(O2CCF3)4, J. Chem. Soc., Chem. Commun., 1982, 752. [all data]

Coleman, Green, et al., 1979
Coleman, A.W.; Green, J.C.; Hayes, A.J.; Seddon, E.A.; Lloyd, D.R.; Niwa, Y., A comparison of the electronic structure of some group 6A dimetal tetracarboxylates using photoelectron spectroscopy, J. Chem. Soc. Dalton Trans., 1979, 75, 1057. [all data]


Notes

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