Dimethyl trisulfide
- Formula: C2H6S3
- Molecular weight: 126.264
- IUPAC Standard InChI: InChI=1S/C2H6S3/c1-3-5-4-2/h1-2H3
- IUPAC Standard InChIKey: YWHLKYXPLRWGSE-UHFFFAOYSA-N
- CAS Registry Number: 3658-80-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Trisulfide, dimethyl; Methyl trisulfide; CH3SSSCH3; 2,3,4-Trithiapentane; Dimethyl trisulphide; 1,3-Dimethyltrisulfane; dimethyl trisufide; DMTS
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Options:
Normal alkane RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | Optima-5 MS | HP-5 MS | HP-5 MS | VF-5 MS | VF-5 MS |
| Column length (m) | 30. | 30. | 30. | 60. | 60. |
| Carrier gas | Helium | Helium | Helium | Helium | Helium |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.32 | 0.32 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 35. | 35. | 50. | 30. | 30. |
| Tend (C) | 250. | 300. | 320. | 260. | 260. |
| Heat rate (K/min) | 10. | 3. | 5. | 2. | 2. |
| Initial hold (min) | 3. | 5. | 5. | ||
| Final hold (min) | 5. | 15. | 28. | 28. | |
| I | 971. | 962. | 969. | 968. | 972. |
| Reference | Goeminne, Vandendriessche, et al., 2012 | Kotowska, Zalikowski, et al., 2012 | Nawrath, Mgode, et al., 2012 | Leffingwell and Alford, 2011 | Leffingwell and Alford, 2011 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5 MS | DB-5 MS | DB-5 MS | HP-101 | HP-101 |
| Column length (m) | 30. | 30. | 30. | 25. | 25. |
| Carrier gas | Helium | Helium | Helium | Helium | Helium |
| Substrate | |||||
| Column diameter (mm) | 0.32 | 0.32 | 0.32 | 0.20 | 0.20 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 50. | 40. | 40. | 70. | 70. |
| Tend (C) | 240. | 230. | 250. | 200. | 200. |
| Heat rate (K/min) | 4. | 6. | 6. | 3. | 3. |
| Initial hold (min) | 2. | 2. | 2. | 2. | 2. |
| Final hold (min) | 10. | 20. | 20. | ||
| I | 969. | 966. | 975. | 969. | 969. |
| Reference | Pino, Marquez, et al., 2010 | Chen, Song, et al., 2009 | Chen, Song, et al., 2009 | Blazevic and Mastelic, 2008 | Blazevic and Mastelic, 2008 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-1 | HP-1 | RTX-5 | SPB-1 | DB-5 |
| Column length (m) | 50. | 50. | 30. | 30. | 30. |
| Carrier gas | Helium | Helium | He | Helium | He |
| Substrate | |||||
| Column diameter (mm) | 0.20 | 0.20 | 0.25 | 0.32 | 0.32 |
| Phase thickness (μm) | 0.33 | 0.33 | 0.25 | 0.25 | 1. |
| Tstart (C) | 60. | 60. | 40. | 40. | 40. |
| Tend (C) | 250. | 250. | 250. | 220. | 250. |
| Heat rate (K/min) | 2. | 2. | 20. | 2. | 4. |
| Initial hold (min) | 5. | 2. | 2. | ||
| Final hold (min) | 20. | 20. | 15. | ||
| I | 943. | 946. | 971. | 935. | 976. |
| Reference | Breme, Langle, et al., 2008 | Breme, Langle, et al., 2008 | Pham, Schilling, et al., 2008 | Rao, Nagender, et al., 2007 | Fan and Qian, 2006 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | DB-1 | HP-1 | BPX5 | BPX-5 | DB-5 |
| Column length (m) | 30. | 50. | 25. | 25. | 30. |
| Carrier gas | He | He | Helium | He | N2 |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.2 | 0.22 | 0.22 | 0.32 |
| Phase thickness (μm) | 0.25 | 0.5 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 50. | 60. | 50. | 50. | 40. |
| Tend (C) | 265. | 250. | 320. | 320. | 250. |
| Heat rate (K/min) | 2.5 | 2. | 5. | 5. | 4. |
| Initial hold (min) | 1. | 5. | 5. | 2. | |
| Final hold (min) | 20. | 60. | 5. | ||
| I | 934. | 957. | 983. | 981. | 976. |
| Reference | Iranshahi, Amin, et al., 2006 | Bendimerad and Bendiab, 2005 | Dickschat, Bode, et al., 2005 | Dickschat, Martens, et al., 2005 | Fan and Qian, 2005 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | MDN-5 | MDN-5 | CP Sil 5 CB | HP-5 | HP-1 |
| Column length (m) | 60. | 60. | 30. | 30. | 50. |
| Carrier gas | He | He | He | Helium | He |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.32 | 0.2 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.5 |
| Tstart (C) | 40. | 40. | 40. | 40. | 60. |
| Tend (C) | 270. | 270. | 220. | 250. | 220. |
| Heat rate (K/min) | 4. | 4. | 4. | 5. | 2. |
| Initial hold (min) | 4. | 4. | 1. | 2. | |
| Final hold (min) | 5. | 5. | 5. | 40. | |
| I | 975. | 980. | 964. | 976. | 953. |
| Reference | van Loon, Linssen, et al., 2005 | van Loon, Linssen, et al., 2005 | Rohloff and Bones, 2005 | N/A | Valette, Fernandez, et al., 2003 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | RSL-200 | DB-5 | DB-5MS | DB-5MS | DB-5 |
| Column length (m) | 30. | 30. | 60. | 30. | 30. |
| Carrier gas | H2 | He | He | He | He |
| Substrate | |||||
| Column diameter (mm) | 0.32 | 0.32 | 0.25 | 0.32 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 50. | 40. | 40. | 40. | 60. |
| Tend (C) | 280. | 230. | 200. | 195. | 240. |
| Heat rate (K/min) | 6. | 6. | 2. | 5. | 3. |
| Initial hold (min) | 5. | 2. | 5. | 5. | |
| Final hold (min) | 5. | 5. | 30. | 40. | |
| I | 950. | 970. | 970. | 967. | 972. |
| Reference | Jirovetz, Ngassoum, et al., 2002 | Sanz, Czerny, et al., 2002 | Lee, Suriyaphan, et al., 2001 | Suriyaphan, Drake, et al., 2001 | Tellez, Schrader, et al., 2001 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5 | SE-54 | HP-5 | DB-1 | HP-1 |
| Column length (m) | 50. | 25. | 30. | 60. | 25. |
| Carrier gas | N2 | H2 | |||
| Substrate | |||||
| Column diameter (mm) | 0.32 | 0.31 | 0.25 | 0.25 | 0.32 |
| Phase thickness (μm) | 0.52 | 0.25 | 0.17 | ||
| Tstart (C) | 35. | 35. | 40. | 30. | 40. |
| Tend (C) | 250. | 250. | 240. | 200. | 200. |
| Heat rate (K/min) | 2. | 4. | 4. | 4. | 5. |
| Initial hold (min) | 15. | 3. | 3. | 25. | |
| Final hold (min) | 45. | 10. | 20. | ||
| I | 972. | 964. | 970. | 941. | 935. |
| Reference | Boylston and Viniyard, 1998 | Ding, Deng, et al., 1998 | Kubec, Drhová, et al., 1998 | Buttery, Ling, et al., 1997 | Lopes, Godoy, et al., 1997 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | DB-1 | DB-1 | SE-54 | SE-54 | SE-54 |
| Column length (m) | 30. | 30. | 25. | 30. | 30. |
| Carrier gas | He | He | He | ||
| Substrate | |||||
| Column diameter (mm) | 0.2 | 0.2 | 0.2 | 0.52 | 0.52 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.5 | 1.5 | 1.5 |
| Tstart (C) | 50. | 50. | 35. | 5. | 5. |
| Tend (C) | 200. | 200. | 250. | 230. | 230. |
| Heat rate (K/min) | 4. | 4. | 5. | 6. | 6. |
| Initial hold (min) | 2. | 2. | 2. | ||
| Final hold (min) | |||||
| I | 963. | 958. | 969. | 977. | 957. |
| Reference | Rapior, Breheret, et al., 1997 | Rapior, Breheret, et al., 1997 | Bellesia, Pinetti, et al., 1996 | Milo and Grosch, 1996 | Milo and Grosch, 1996 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | DB-1 | RTX-5 | OV-101 | OV-101 | DB-1 |
| Column length (m) | 30. | 30. | 50. | 50. | 60. |
| Carrier gas | He | He | N2 | N2 | He |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.52 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 1.5 | 1. | ||
| Tstart (C) | 35. | 5. | 80. | 80. | 40. |
| Tend (C) | 150. | 230. | 200. | 200. | 260. |
| Heat rate (K/min) | 5. | 6. | 2. | 2. | 2. |
| Initial hold (min) | 5. | ||||
| Final hold (min) | 60. | ||||
| I | 931. | 977. | 940. | 949. | 957. |
| Reference | Hanum, Sinha, et al., 1995 | Milo and Grosch, 1995 | Tamura, Nakamoto, et al., 1995 | Tamura, Nakamoto, et al., 1995 | Yu and Ho, 1995 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | DB-1 | DB-1 | DB-1 | DB-1 | DB-5 |
| Column length (m) | 60. | 60. | 60. | 60. | 30. |
| Carrier gas | He | He | He | He | |
| Substrate | |||||
| Column diameter (mm) | 0.32 | 0.25 | 0.32 | 0.32 | 0.2 |
| Phase thickness (μm) | 1. | 0.25 | |||
| Tstart (C) | 30. | 40. | 60. | 30. | 30. |
| Tend (C) | 200. | 260. | 220. | 200. | 200. |
| Heat rate (K/min) | 4. | 2. | 3. | 4. | 2. |
| Initial hold (min) | 25. | 5. | 25. | ||
| Final hold (min) | 20. | 60. | 20. | ||
| I | 941. | 958. | 950. | 941. | 950. |
| Reference | Buttery, Stern, et al., 1994 | Yu, Wu, et al., 1994 | Güntert, Bertram, et al., 1992 | Hansen, Buttery, et al., 1992 | Sinha, Guyer, et al., 1992 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HG-5 | OV-101 | OV-101 | OV-101 | DB-1 |
| Column length (m) | 50. | 50. | 50. | 50. | 60. |
| Carrier gas | He | He | Nitrogen | Nitrogen | |
| Substrate | |||||
| Column diameter (mm) | 0.32 | 0.32 | 0.25 | 0.25 | 0.32 |
| Phase thickness (μm) | 0.52 | 0.5 | 0.25 | ||
| Tstart (C) | 35. | 50. | 70. | 80. | 50. |
| Tend (C) | 250. | 250. | 200. | 200. | 250. |
| Heat rate (K/min) | 3. | 4. | 2. | 2. | 4. |
| Initial hold (min) | 15. | ||||
| Final hold (min) | 45. | ||||
| I | 979. | 950. | 949. | 952. | 940. |
| Reference | Drumm and Spanier, 1991 | Misharina, Golovnya, et al., 1991 | Sugisawa, Nakamura, et al., 1990 | Sugisawa, Nakamura, et al., 1990 | Flath, Matsumoto, et al., 1989 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary |
|---|---|---|---|
| Active phase | DB-1 | DB-1 | DB-1 |
| Column length (m) | 60. | 60. | 60. |
| Carrier gas | |||
| Substrate | |||
| Column diameter (mm) | 0.32 | 0.32 | 0.32 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 50. | 50. | 50. |
| Tend (C) | 250. | 250. | 250. |
| Heat rate (K/min) | 4. | 4. | 4. |
| Initial hold (min) | |||
| Final hold (min) | |||
| I | 940. | 941. | 941. |
| Reference | Flath, Matsumoto, et al., 1989 | Flath, Matsumoto, et al., 1989 | Flath, Matsumoto, et al., 1989 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Goeminne, Vandendriessche, et al., 2012
Goeminne, P.C.; Vandendriessche, T.; Van Eldere, J.; Nicolai, B.M.; Hertog, M.L.; Dupont, L.J.,
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Nawrath, Mgode, et al., 2012
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Notes
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References
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