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Tricyclo[3.2.1.02,4]oct-6-ene,(1«alpha»,2«beta»,4«beta»,5«alpha»)-


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas55.1 ± 0.1kcal/molChydRoth, Adamczak, et al., 1991 
Deltafgas51.0 ± 1.0kcal/molCcbHassenruck, Martin, et al., 1987 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid40.77 ± 0.33kcal/molCcbHassenruck, Martin, et al., 1987 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Deltavap10.1kcal/molN/AHassenruck, Martin, et al., 1987 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

2Hydrogen + Tricyclo[3.2.1.0(2,4)]oct-6-ene,(1α,2β,4β,5α)- = Bicyclo[2.2.1]heptane, 2-methyl-, exo-

By formula: 2H2 + C8H10 = C8H14

Quantity Value Units Method Reference Comment
Deltar-74.7 ± 0.1kcal/molChydRoth, Adamczak, et al., 1991liquid phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to C8H10+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
8.90PEBischof, Heilbronner, et al., 1971Vertical value

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Roth, Adamczak, et al., 1991
Roth, W.R.; Adamczak, O.; Breuckmann, R.; Lennartz, H.-W.; Boese, R., Die Berechnung von Resonanzenergien; das MM2ERW-Kraftfeld, Chem. Ber., 1991, 124, 2499-2521. [all data]

Hassenruck, Martin, et al., 1987
Hassenruck, K.; Martin, H.-D.; Mayer, B.; Urbanek, T.; Zirwes, T.; Walsh, R.; Beckhaus, H.-D., An Experimental Approach to the C8H10 Hypersurface. Kinetic and Thermochemical Investigations on a Formally Forbidden Ground-state [2«sigma» + 2«pi»] Cycloaddition, Chem. Ber., 1987, 120, 177-186. [all data]

Bischof, Heilbronner, et al., 1971
Bischof, P.; Heilbronner, E.; Prinzbach, H.; Martin, H.D., A photoelectron-spectroscopic investigation of the homoconjugative interaction between «pi»- and Walsh-orbitals in endo- and exo- cyclopropano-norbornene, Helv. Chim. Acta, 1971, 54, 1072. [all data]


Notes

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