Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Methyl hypofluorite


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MM - M. Mautner
LL - S.G. Lias and J.F. Liebman

Gas basicity at 298K

Gas basicity (review) (kJ/mol) Reference Comment
648.0 - 680.5Attina, Cacace, et al., 2001hexaflurobenzene; ethylene. PT bracketing in collision cell (E(collision = 0 eV) of triple quadrupole MS. Authors report PA but GB is bracketed.; MM

Ionization energy determinations

IE (eV) Method Reference Comment
11.340 ± 0.008PIRuscic, Appelman, et al., 1991LL

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH2FO+12.49HPIRuscic, Appelman, et al., 1991LL
CH2O+13.82 ± 0.03(H+F)PIRuscic, Appelman, et al., 1991LL
CH3+<=13.539 ± 0.015FOPIRuscic, Appelman, et al., 1991LL

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Attina, Cacace, et al., 2001
Attina, M.; Cacace, F.; Cartoni, A.; Rosi, M., Gas-phase electrophilic fluorination of methanol by XeF+. Formation and characterization of protonated methyl hypofluorite and hypoxenite, J. Mass Spectrom., 2001, 36, 392. [all data]

Ruscic, Appelman, et al., 1991
Ruscic, B.; Appelman, E.H.; Berkowitz, J., Photoionization mass spectrometric study of CH3OF, J. Chem. Phys., 1991, 95, 7957. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References