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Chromium,dicarbonyl(«eta»5-2,4-cyclopentadien-1-yl)nitrosyl-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Quantity Value Units Method Reference Comment
Proton affinity (review)819.1kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity786.7kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
8.5 ± 0.1EIGreenhough, Kolthammer, et al., 1979LLK
7.80EIMuller and Fenderl, 1971LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C5H5Cr+12.8 ± 0.12CO+NOEIGreenhough, Kolthammer, et al., 1979LLK
C5H5NOCr+10.5 ± 0.12COEIGreenhough, Kolthammer, et al., 1979LLK
C6H5NO2Cr+9.4 ± 0.1COEIGreenhough, Kolthammer, et al., 1979LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Greenhough, Kolthammer, et al., 1979
Greenhough, T.J.; Kolthammer, B.W.S.; Legzdins, P.; Trotter, J., Organometallic nitrosyl chemistry. 10. Synthesis, X-ray structural characterization, and properties of dicarbonyl («eta»5-cyclopentadienyl)(thionitrosyl)chromium, Inorg. Chem., 1979, 18, 3548. [all data]

Muller and Fenderl, 1971
Muller, J.; Fenderl, K., Sekundar-ionen in den Massenspektren von Organochrom-Komplexen, Chem. Ber., 1971, 104, 2199. [all data]


Notes

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