Thioformyl radical


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas71.7 ± 2.0kcal/molIonRuscic and Berkowitz, 1993 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman

View reactions leading to CHS+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
Δf(+) ion243.kcal/molN/AN/A 

Ionization energy determinations

IE (eV) Method Reference Comment
7.412 ± 0.005PIRuscic and Berkowitz, 1993, 2LL
≤7.499 ± 0.005PIRuscic and Berkowitz, 1993, 2LL
>7.3DERLias, Bartmess, et al., 1988LL

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ruscic and Berkowitz, 1993
Ruscic, B.; Berkowitz, J., Photoionization mass spectrometry of CH2S and HCS, J. Chem. Phys., 1993, 98, 2568-2579. [all data]

Ruscic and Berkowitz, 1993, 2
Ruscic, B.; Berkowitz, J., Photoionization mass spectrometry of CH2S and HCS, J. Chem. Phys., 1993, 98, 2568. [all data]

Lias, Bartmess, et al., 1988
Lias, S.G.; Bartmess, J.E.; Liebman, J.F.; Holmes, J.L.; Levin, R.D.; Mallard, W.G., Gas-phase ion and neutral thermochemistry, J. Phys. Chem. Ref. Data, Suppl. 1, 1988, 17, 1-861. [all data]


Notes

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