perfluorohexadecane

• Formula: C₁₆F₃₄
• Molecular weight: 838.1169
• CAS Registry Number: 355-49-7
• Information on this page:
  • Condensed phase thermochemistry data
  • Phase change data
  • References
  • Notes
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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of solid

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of sublimation

Enthalpy of fusion

Entropy of fusion

Enthalpy of phase transition

Entropy of phase transition

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lebedev, Bykova, et al., 1993
Lebedev, B.V.; Bykova, T.A.; Vasil'ev, V.G.; Wunderlich, B., Heat Capacity and thermodynamic functions of a series of n-perfluororalkanes in the range 0-320 K, Zhur. Khim. Termodin. Termokhim. 2, 1993, (1), 62-79. [all data]

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Jin, Boller, et al., 1994
Jin, Y.; Boller, A.; Wunderlich, B.; Lebedev, B.V., Heat capacities and transitions in n-perfluoroalkanes and poly(tetrafluoroethylene), Thermochim. Acta, 1994, 234, 103-25. [all data]

Starkweather, 1986
Starkweather, H.W., Jr., Melting and crystalline transitions in normal perfluoroalkanes and poly(tetrafluoroethylene), Marcomolecules, 1986, 19, 4, 1131, https://doi.org/10.1021/ma00158a034 . [all data]

Segwichert, 1984
Segwichert, H., , Dissertation, Johannes Gutenberg Univ.,Mainz, 1984. [all data]

Bradley and Waghorn, 1951
Bradley, R.S.; Waghorn, G.C.S., The Rate of Evaporation of Droplets. V. Evaporation Characteristics of Some Branched-Chain Hydrocarbons and a Straight-Chain Fluorocarbon, Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, 1951, 206, 1084, 65-72, https://doi.org/10.1098/rspa.1951.0056 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Starkweather, 1986, 2
Starkweather, Howard W., Melting and crystalline transitions in normal perfluoroalkanes and poly(tetrafluoroethylene), Macromolecules, 1986, 19, 4, 1131-1134, https://doi.org/10.1021/ma00158a034 . [all data]

Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, References

• Symbols used in this document:
  

  Cp,solid	Constant pressure heat capacity of solid
  S°solid,1 bar	Entropy of solid at standard conditions (1 bar)
  Tboil	Boiling point
  Tfus	Fusion (melting) point
  ΔHtrs	Enthalpy of phase transition
  ΔStrs	Entropy of phase transition
  ΔfusH	Enthalpy of fusion
  ΔfusS	Entropy of fusion
  ΔsubH	Enthalpy of sublimation

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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