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Perfluoro(methylcyclohexane)

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-2897.2 ± 3.8kJ/molCcrGood, Douslin, et al., 1959Reanalyzed by Cox and Pilcher, 1970, Original value = -2825. kJ/mol; produce 3HF(aq:10)

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-2931.1 ± 3.8kJ/molCcrGood, Douslin, et al., 1959Reanalyzed by Cox and Pilcher, 1970, Original value = -2859. kJ/mol; produce 3HF(aq:10); ALS
Quantity Value Units Method Reference Comment
Deltacliquid-1844.9 ± 0.46kJ/molCcrGood, Douslin, et al., 1959produce 3HF(aq:10); ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
353.1298.Yarrington and Kay, 1957T = 298 to 373 K. Equation only.; DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Chlorine anion + Perfluoro(methylcyclohexane) = (Chlorine anion bullet Perfluoro(methylcyclohexane))

By formula: Cl- + C7F14 = (Cl- bullet C7F14)

Quantity Value Units Method Reference Comment
Deltar<7.53kJ/molIMRBChowdhury and Kebarle, 1986gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
7.5300.PHPMSChowdhury and Kebarle, 1986gas phase; DG<; M

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Good, Douslin, et al., 1959
Good, W.D.; Douslin, D.R.; Scott, D.W.; George, A.; Lacina, J.L.; Dawson, J.P.; Waddington, G., Thermochemistry and vapor pressure of aliphatic fluorocarbons. A comparison of the C-F and C-H thermochemical bond energies, J. Phys. Chem., 1959, 63, 1133-1138. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Yarrington and Kay, 1957
Yarrington, R.M.; Kay, W.B., The liquid specific heats of some fluorocarbon compounds, J. Phys. Chem., 1957, 61, 1259-1260. [all data]

Chowdhury and Kebarle, 1986
Chowdhury, S.; Kebarle, P., Role of Binding Energies in A-.B and A.B- Complexes in the Kinetics of Gas Phase Electron Transfer Reactions:A- + B = A + B- Involving Perfluoro Compounds: SF6, C6F11CF3, J. Chem. Phys., 1986, 85, 9, 4989, https://doi.org/10.1063/1.451687 . [all data]


Notes

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