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1,2-Dibromo-1-chloro-1,2,2-trifluoroethane

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil366. - 367.KN/APCR Inc., 1990BS
Tboil366.KN/AMajer and Svoboda, 1985 
Quantity Value Units Method Reference Comment
Tc560.7KN/AMajer and Svoboda, 1985 
Quantity Value Units Method Reference Comment
Deltavap35.11kJ/molN/AMajer and Svoboda, 1985 
Deltavap35.0 ± 0.1kJ/molCMajer, Svoboda, et al., 1981AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
31.17366.N/AMajer and Svoboda, 1985 
31.4358.AStephenson and Malanowski, 1987Based on data from 343. - 428. K.; AC
34.2 ± 0.1313.CMajer, Svoboda, et al., 1981AC
33.5 ± 0.1328.CMajer, Svoboda, et al., 1981AC
32.6 ± 0.1343.CMajer, Svoboda, et al., 1981AC
31.6 ± 0.1358.CMajer, Svoboda, et al., 1981AC

Enthalpy of vaporization

ΔvapH = A exp(-βTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kJ/mol)
    Tr = reduced temperature (T / Tc)

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Temperature (K) A (kJ/mol) beta Tc (K) Reference Comment
298. - 358.50.190.2786560.7Majer and Svoboda, 1985 

Reaction thermochemistry data

Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Bromine + Ethene, chlorotrifluoro- = 1,2-Dibromo-1-chloro-1,2,2-trifluoroethane

By formula: Br2 + C2ClF3 = C2Br2ClF3

Quantity Value Units Method Reference Comment
Deltar-132.3kJ/molCmLacher, Casali, et al., 1956gas phase; Heat of bromination

1,2-Dibromo-1-chloro-1,2,2-trifluoroethane = Bromine + Ethene, chlorotrifluoro-

By formula: C2Br2ClF3 = Br2 + C2ClF3

Quantity Value Units Method Reference Comment
Deltar132.25kJ/molCmLacher, Casali, et al., 1956gas phase

Mass spectrum (electron ionization)

Go To: Top, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-IW-4786
NIST MS number 237387

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References

Go To: Top, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Majer, Svoboda, et al., 1981
Majer, Vladimír; Svoboda, Václav; Posta, Antonín; Pick, Jirí, Determination of heats of vaporization and some other thermodynamic quantities for three fluorinated halogen ethanes, Collect. Czech. Chem. Commun., 1981, 46, 4, 817-822, https://doi.org/10.1135/cccc19810817 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Lacher, Casali, et al., 1956
Lacher, J.R.; Casali, L.; Park, J.D., Reaction heats of organic halogen compounds V. The vapor phase bromination of tetrafluoroethylene and trifluorochloroethylene, J. Phys. Chem., 1956, 60, 608-610. [all data]


Notes

Go To: Top, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References