Borane, fluorodimethyl-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Fluorine anion + C2H6BF = (Fluorine anion • C2H6BF)

By formula: F- + C2H6BF = (F- • C2H6BF)

Quantity Value Units Method Reference Comment
Δr258.6kJ/molIMRBMurphy and Beauchamp, 1977gas phase; Fluoride Affinity: Et3B > Me2BF > MeSiF3 > Me3B > SF4

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Murphy and Beauchamp, 1977
Murphy, M.K.; Beauchamp, J.L., Fluorine and Alkyl Substituent Effects on Gas-Phase Lewis Acidities of Boranes by ICR Spectroscopy, Inorg. Chem., 1977, 16, 2437. [all data]


Notes

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