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(Ch3)3(tert-c4H9)sn


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-64.0 ± 6.2kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafsolid-118.0 ± 4.5kJ/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Deltacsolid-5786.7 ± 4.4kJ/molCC-SBColeman and Skinner, 1966Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltasub54.0 ± 4.2kJ/molCC-SBColeman and Skinner, 1966 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.34 ± 0.11EILappert, Pedley, et al., 1971LLK
8.34 ± 0.11EILappert, Simpson, et al., 1969RDSH
8.50PEKochi, 1980Vertical value; LLK
8.65PEHosomi and Traylor, 1975Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C3H9Sn+9.32 ± 0.16(CH3)3CEILappert, Pedley, et al., 1971LLK
C3H9Sn+9.32 ± 0.16?EILappert, Simpson, et al., 1969RDSH
C3H9Sn+9.50 ± 0.10?EIYergey and Lampe, 1968RDSH
C4H9+10.03 ± 0.23(CH3)3SnEILappert, Pedley, et al., 1971LLK
C4H9+10.03 ± 0.23?EILappert, Simpson, et al., 1969RDSH
C6H15Sn+10.95 ± 0.19CH3EIYergey and Lampe, 1968RDSH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Coleman and Skinner, 1966
Coleman, D.J.; Skinner, H.A., Thermochemistry of metallic alkyls. Part 15.?Heats of combustion of trimethyl-isopropyl tin, trimethyl-t-butyl tin and tetra-isopropyl tin, Trans. Faraday Soc., 1966, 62, 1721, https://doi.org/10.1039/tf9666201721 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Lappert, Pedley, et al., 1971
Lappert, M.F.; Pedley, J.B.; Simpson, J.; Spalding, T.R., Bonding studies of compounds of boron and the Group IV elements. VI. Mass spectrometric studies on compounds Me4M and Me3M-M'Me3 (M and M'=C, Si, Ge, Sn, and Pb): thermochemical data, J. Organomet. Chem., 1971, 29, 195. [all data]

Lappert, Simpson, et al., 1969
Lappert, M.F.; Simpson, J.; Spalding, T.R., Bonding studies of compounds of the group IV elements: ionisation potentials of the Me3M radicals, J.Organometal. Chem., 1969, 17, PI. [all data]

Kochi, 1980
Kochi, J.K., The role of electron transfer and charge transfer in organometallic chemistry, Pure Appl. Chem., 1980, 52, 571. [all data]

Hosomi and Traylor, 1975
Hosomi, A.; Traylor, T.G., Studies of interactions of adjacent carbon-metal «sigma» bonds by photoelectron spectroscopy, J. Am. Chem. Soc., 1975, 97, 3682. [all data]

Yergey and Lampe, 1968
Yergey, A.L.; Lampe, F.W., An electron impact study of ionization and dissociation of trimethylstannanes, J. Organometal. Chem., 1968, 15, 339. [all data]


Notes

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