Stannane, trimethylpropyl-
- Formula: C6H16Sn
- Molecular weight: 206.901
- IUPAC Standard InChIKey: GDLIQYVPJMAUEA-UHFFFAOYSA-N
- CAS Registry Number: 3531-45-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Propyltrimethylstannane; Propyltrimethyltin; Trimethylpropylstannane; Trimethyl propyl tin
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Phase change data
Go To: Top, Gas phase ion energetics data, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
43.8 | 276. | N/A | Stull, 1947 | Based on data from 261. to 405. K. |
41.4 | 307. | I | Bullard and Haussmann, 1929 | Based on data from 286. to 328. K. |
38.0 | 366. | I | Bullard and Haussmann, 1929 | Based on data from 328. to 405. K. |
Gas phase ion energetics data
Go To: Top, Phase change data, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.54 ± 0.01 | EI | Yergey and Lampe, 1968 | RDSH |
9.1 | PE | Kochi, 1980 | Vertical value; LLK |
8.9 | PE | Hosomi and Traylor, 1975 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C3H9Sn+ | 9.50 ± 0.06 | ? | EI | Yergey and Lampe, 1965 | RDSH |
C5H13Sn+ | 9.59 ± 0.07 | CH3 | EI | Yergey and Lampe, 1968 | RDSH |
Gas Chromatography
Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Packed | Apiezon L | 190. | 833. | Putnam and Pu, 1965 | Celite; Column length: 1. m |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Packed | Apiezon L | 799. | Putnam and Pu, 1965, 2 | Celite, 10. K/min; Column length: 3. m; Tstart: 60. C |
Packed | Apiezon L | 801. | Putnam and Pu, 1965, 2 | Celite, 15. K/min; Column length: 3. m; Tstart: 60. C |
Packed | Apiezon L | 799. | Putnam and Pu, 1965, 2 | Celite, 6. K/min; Column length: 3. m; Tstart: 60. C |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Stull, 1947
Stull, Daniel R.,
Vapor Pressure of Pure Substances. Organic and Inorganic Compounds,
Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022
. [all data]
Bullard and Haussmann, 1929
Bullard, R.H.; Haussmann, A.C.,
The Vapor Pressure of Some Stannanes,
J. Phys. Chem., 1929, 34, 4, 743-747, https://doi.org/10.1021/j150310a006
. [all data]
Yergey and Lampe, 1968
Yergey, A.L.; Lampe, F.W.,
An electron impact study of ionization and dissociation of trimethylstannanes,
J. Organometal. Chem., 1968, 15, 339. [all data]
Kochi, 1980
Kochi, J.K.,
The role of electron transfer and charge transfer in organometallic chemistry,
Pure Appl. Chem., 1980, 52, 571. [all data]
Hosomi and Traylor, 1975
Hosomi, A.; Traylor, T.G.,
Studies of interactions of adjacent carbon-metal σ bonds by photoelectron spectroscopy,
J. Am. Chem. Soc., 1975, 97, 3682. [all data]
Yergey and Lampe, 1965
Yergey, A.L.; Lampe, F.W.,
An electron impact study of the bond dissociation energies of some trimethyltin compounds,
J. Am. Chem. Soc., 1965, 87, 4204. [all data]
Putnam and Pu, 1965
Putnam, R.C.; Pu, H.,
Retention indices of organotins,
J. Gas Chromatogr., 1965, 3, 5, 160-164, https://doi.org/10.1093/chromsci/3.5.160
. [all data]
Putnam and Pu, 1965, 2
Putnam, R.C.; Pu, H.,
Retention indices of organotins (II),
J. Gas Chromatogr., 1965, 3, 9, 289-293, https://doi.org/10.1093/chromsci/3.9.289
. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, Gas Chromatography, References
- Symbols used in this document:
AE Appearance energy ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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