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CH2F


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CHF- + Hydrogen cation = CH2F

By formula: CHF- + H+ = CH2F

Quantity Value Units Method Reference Comment
Deltar1668. ± 6.3kJ/molG+TSBorn, Ingemann, et al., 1994gas phase; Between EtNH2 and Me2NH
Deltar1650. ± 22.kJ/molD-EAGilles, Ervin, et al., 1992gas phase; Triplet state of neutral: 14.9±0.4 kcal/mol higher than singlet
Quantity Value Units Method Reference Comment
Deltar1634. ± 5.9kJ/molIMRBBorn, Ingemann, et al., 1994gas phase; Between EtNH2 and Me2NH
Deltar1616. ± 22.kJ/molH-TSGilles, Ervin, et al., 1992gas phase; Triplet state of neutral: 14.9±0.4 kcal/mol higher than singlet

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Born, Ingemann, et al., 1994
Born, M.; Ingemann, S.; Nibbering, N.M.M., Heats of formation of mono-halogen-substituted carbenes. Stability and reactivity of CHX(center dot-) (X=F, Cl, Pr, and I) radical anions, J. Am. Chem. Soc., 1994, 116, 16, 7210, https://doi.org/10.1021/ja00095a025 . [all data]

Gilles, Ervin, et al., 1992
Gilles, M.K.; Ervin, K.M.; Ho, J.; Lineberger, W.C., Negative Ion Photoelectron Spectroscopy of HCF-, HCCl-, HCBr-, and HCI- - Photoelectron Angular Distributions and Neutral Triplet Excitation, J. Phys. Chem., 1992, 96, 3, 1130, https://doi.org/10.1021/j100182a021 . [all data]


Notes

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