7-Tetradecyne

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Gas phase ion energetics data

Go To: Top, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
9.03 ± 0.04PIRang and Martinson, 1978LLK
9.067 ± 0.005PECarlier, Dubois, et al., 1975LLK

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Additional Data

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Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center
State gas
Instrument HP-GC/MS/IRD

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

Go To: Top, Gas phase ion energetics data, IR Spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin S.A. Rang et al., IR & MS of Unsatd. Hydrocarbons, 1977
NIST MS number 142654

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryOV-101110.1416.Kuningas, Rang, et al., 1990He; Column length: 50. m; Column diameter: 0.25 mm
CapillaryApiezon L150.1400.Rang, Kuningas, et al., 1976N2; Column length: 50. m; Column diameter: 0.25 mm
CapillaryApiezon L170.1400.Rang, Kuningas, et al., 1976N2; Column length: 50. m; Column diameter: 0.25 mm
CapillaryApiezon L190.1401.Rang, Kuningas, et al., 1976N2; Column length: 50. m; Column diameter: 0.25 mm

Kovats' RI, polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryPEG-20M80.1545.1Orav, Kuningas, et al., 1993100. m/0.25 mm/0.12 μm
CapillaryPEG-20M80.1562.3Orav, Kuningas, et al., 1993100. m/0.25 mm/0.24 μm
CapillaryPEG-20M80.1563.Orav, Kuningas, et al., 199360. m/0.32 mm/0.25 μm
CapillaryPEG 4000110.1572.Rang, Orav, et al., 1988 
CapillaryPEG 4000120.1572.Rang, Orav, et al., 1988 
CapillaryPEG 4000140.1574.Rang, Orav, et al., 1988 
CapillaryPEG 4000150.1574.Rang, Orav, et al., 1988 
CapillaryPEG 4000160.1575.Rang, Orav, et al., 1988 
CapillaryPEG-20M70.1541.3Orav, Kuningas, et al., 1985Column length: 100. m; Column diameter: 0.25 mm
CapillaryPEG-20M80.1545.1Orav, Kuningas, et al., 1985Column length: 100. m; Column diameter: 0.25 mm
CapillaryPEG-20M80.1562.3Orav, Kuningas, et al., 1985Column length: 100. m; Column diameter: 0.25 mm

References

Go To: Top, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rang and Martinson, 1978
Rang, S.; Martinson, E., Ionization potentials of unsaturated hydrocarbons. 3. n-Alkyunes C8-C12., Eesti. NSV Tead. Akad. Toim. Keem., 1978, 44. [all data]

Carlier, Dubois, et al., 1975
Carlier, P.; Dubois, J.E.; Masclet, P.; Mouvier, G., Spectres de photoelectrons des alcynes, J. Electron Spectrosc. Relat. Phenom., 1975, 7, 55. [all data]

Kuningas, Rang, et al., 1990
Kuningas, K.; Rang, S.; Kailas, T., Relationship between the structure and retention of n-alkenes and n-alkynes on silicone phases, J. Chromatogr., 1990, 520, 137-148, https://doi.org/10.1016/0021-9673(90)85094-C . [all data]

Rang, Kuningas, et al., 1976
Rang, S.; Kuningas, K.; Orav, A.; Eisen, O., Capillary gas chromatography of n-alkynes. I. Retention indices, J. Chromatogr., 1976, 119, 451-460, https://doi.org/10.1016/S0021-9673(00)86807-7 . [all data]

Orav, Kuningas, et al., 1993
Orav, A.; Kuningas, K.; Rang, S., A comparison of different retention index systems with unsaturated and aromatic hydrocarbons in capillary gas chromatography on PEG 20MK, Chromatographia, 1993, 37, 7/8, 411-414, https://doi.org/10.1007/BF02272257 . [all data]

Rang, Orav, et al., 1988
Rang, S.A.; Orav, A.E.; Kuningas, K.R.; Meister, A.E.; Strense, T.V.; Eisen, O.G., Gas-Chromatographic Characteristics of unsaturated hydrocarbons, Academy of Sciences of Estonia SSR, Tallinn, Estonia SSR, 1988, 208. [all data]

Orav, Kuningas, et al., 1985
Orav, A.; Kuningas, K.; Rang, S.; Eisen, O., Capillary gas chromatography of n-tridecenes, n-tetradecenes and C10-C14 n-alkynes on polyethylene glycol 20m of different polarity, Eesti NSV Tead. Akad. Toim. Keem., 1985, 34, 2, 105-113. [all data]


Notes

Go To: Top, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References