C6F5CH3+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 21900 gas Bondybey and Miller, 1983
To = 21751 Ne B-X 410 475 Bondybey, Miller, et al., 1980
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1546 Ne LF Bondybey, Miller, et al., 1980
1463 Ne LF Bondybey, Miller, et al., 1980
537 Ne LF Bondybey, Miller, et al., 1980
426 Ne LF Bondybey, Miller, et al., 1980
274 Ne LF Bondybey, Miller, et al., 1980

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 277 T Ne LF Bondybey, Miller, et al., 1980

Additional references: Jacox, 1994, page 441; Bondybey, Vaughn, et al., 1981

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bondybey and Miller, 1983
Bondybey, V.E.; Miller, T.A., Molecular Ions: Spectroscopy, Structure, and Chemistry, pp. 125-173, North-Holland, Amsterdam, 1983. [all data]

Bondybey, Miller, et al., 1980
Bondybey, V.E.; Miller, T.A.; English, J.H., J. Chim. Phys., 1980, 77, 667. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Bondybey, Vaughn, et al., 1981
Bondybey, V.E.; Vaughn, C.R.; Miller, T.A.; English, J.H.; Shiley, R.H., Halogenated benzene radical cations and ground state degeneracy splitting by asymmetric substitution, J. Chem. Phys., 1981, 74, 12, 6584, https://doi.org/10.1063/1.441120 . [all data]

Notes

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