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C6H5F+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   H,I


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 57900 ± 1000 gas Bieri, Asbrink, et al., 1981

State:   G


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 48250 ± 1000 gas Bieri, Asbrink, et al., 1981

State:   F


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 43400 ± 1000 gas Bieri, Asbrink, et al., 1981

State:   E


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 37680 ± 160 gas Bieri, Asbrink, et al., 1981

State:   D


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 30500 ± 1000 gas Bieri, Asbrink, et al., 1981

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 24800 ± 1000 gas Bieri, Asbrink, et al., 1981
To = 23220 Ar C-X 410 435 Keelan and Andrews, 1981
Lurito and Andrews, 1985


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 510 Ar AB Lurito and Andrews, 1985

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 21075 gas B-X 440 490 Bieri, Asbrink, et al., 1981
Walter, Boesl, et al., 1989
Anand, LeClaire, et al., 1999


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 9a 1152 gas PF PRI Walter, Boesl, et al., 1989
Anand, LeClaire, et al., 1999
12 695 gas PRI Anand, LeClaire, et al., 1999
6a 458 gas PF PRI Walter, Boesl, et al., 1989
Anand, LeClaire, et al., 1999
a2 16a 236 gas PRI Anand, LeClaire, et al., 1999
b1 366 gas PRI Anand, LeClaire, et al., 1999
11 207 gas PRI Anand, LeClaire, et al., 1999
b2 6b 520 gas PRI Anand, LeClaire, et al., 1999
18b 430 gas PRI Anand, LeClaire, et al., 1999

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 4680 ± 1000 gas Bieri, Asbrink, et al., 1981

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 8a 1610 gas TPI TPE Walter, Scherm, et al., 1991
Takahashi, Ohashi, et al., 1992
Kwon, Kim, et al., 2002
19a 1502 gas TPI Kwon, Kim, et al., 2002
7a 1274 gas TPI Kwon, Kim, et al., 2002
9a 1168 gas TPE TPI Walter, Scherm, et al., 1991
Takahashi, Ohashi, et al., 1992
Lembach and Brutschy, 1996
Kwon, Kim, et al., 2002
1 983 gas MPI TPE Walter, Scherm, et al., 1991
Takahashi, Ohashi, et al., 1992
18a 959 gas TPE PI Walter, Scherm, et al., 1991
Takahashi, Ohashi, et al., 1992
Lembach and Brutschy, 1996
12 804 gas TPE TPI Walter, Boesl, et al., 1989
Walter, Scherm, et al., 1991
Takahashi, Ohashi, et al., 1992
Lembach and Brutschy, 1996
Kwon, Kim, et al., 2002
6a 500 ± 2 gas TPE TPI Bieri, Asbrink, et al., 1981
Walter, Boesl, et al., 1989
Takahashi, Ohashi, et al., 1992
Lembach and Brutschy, 1996
Kwon, Kim, et al., 2002
a2 16a 341 gas TPI Anand, LeClaire, et al., 1999
b1 10b 763 gas TPI Kwon, Kim, et al., 2002
16b 479 gas TPI Kwon, Kim, et al., 2002
11 182 gas TPI Lembach and Brutschy, 1996
Kwon, Kim, et al., 2002
b2 8b 1574 gas TPI Kwon, Kim, et al., 2002
19b 1464 gas TPI Kwon, Kim, et al., 2002
14 1339 gas TPI Kwon, Kim, et al., 2002
3 1299 gas TPI Kwon, Kim, et al., 2002
9b 1106 gas TPI Kwon, Kim, et al., 2002
15 1071 gas TPI Kwon, Kim, et al., 2002
6b 606 gas TPI Kwon, Kim, et al., 2002
18b 402 gas TPE TPI Walter, Scherm, et al., 1991
Takahashi, Ohashi, et al., 1992
Lembach and Brutschy, 1996
Kwon, Kim, et al., 2002

Additional references: Jacox, 1994, page 428; Jacox, 2003, page 397; Ford and Muller-Dethlefs, 2004

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bieri, Asbrink, et al., 1981
Bieri, G.; Asbrink, L.; Von Niessen, W., 30.4 nm He(II) photoelectron spectra of organic molecules. Part IV. Fluoro-compounds (C,H,F), J. Electron Spectrosc. Relat. Phenom., 1981, 23, 281. [all data]

Keelan and Andrews, 1981
Keelan, B.W.; Andrews, L., Visible absorption spectra and two-photon photodissociation of halobenzene cations in solid argon, J. Am. Chem. Soc., 1981, 103, 4, 829, https://doi.org/10.1021/ja00394a016 . [all data]

Lurito and Andrews, 1985
Lurito, J.T.; Andrews, L., Vibronic absorption spectra of fluorobenzene and difluorobenzene radical cations in solid argon, Chem. Phys., 1985, 97, 1, 121, https://doi.org/10.1016/0301-0104(85)87084-1 . [all data]

Walter, Boesl, et al., 1989
Walter, K.; Boesl, U.; Schlag, E.W., Molecular ion spectroscopy: Resonance-enhanced multiphoton dissociation spectra of the fluorobenzene cation, Chem. Phys. Lett., 1989, 162, 4-5, 261, https://doi.org/10.1016/0009-2614(89)87041-1 . [all data]

Anand, LeClaire, et al., 1999
Anand, R.; LeClaire, J.E.; Johnson, P.M., Photoinduced Rydberg Ionization (PIRI) Spectroscopy of the B State of the Fluorobenzene Cation, J. Phys. Chem. A, 1999, 103, 15, 2618, https://doi.org/10.1021/jp984697a . [all data]

Walter, Scherm, et al., 1991
Walter, K.; Scherm, K.; Boesl, U., Spectroscopy of the ionic ground state of monohalogenated benzenes, J. Phys. Chem., 1991, 95, 3, 1188, https://doi.org/10.1021/j100156a029 . [all data]

Takahashi, Ohashi, et al., 1992
Takahashi, K.; Ohashi, K.; Nishi, N., Mem. Fac. Sci. Kyushu Univ., 1992, Ser. C, 18 161. [all data]

Kwon, Kim, et al., 2002
Kwon, C.H.; Kim, H.L.; Kim, M.S., Vibrational spectra of halobenzene cations in the ground and B [sup 2]B[sub 2] electronic states obtained by one-photon mass-analyzed threshold ionization spectrometry, J. Chem. Phys., 2002, 116, 23, 10361, https://doi.org/10.1063/1.1478695 . [all data]

Lembach and Brutschy, 1996
Lembach, G.; Brutschy, B., Fragmentation Energetics and Dynamics of the Neutral and Ionized Fluorobenzene·Ar Cluster Studied by Mass Analyzed Threshold Ionization Spectroscopy, J. Phys. Chem., 1996, 100, 51, 19758, https://doi.org/10.1021/jp9621179 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Ford and Muller-Dethlefs, 2004
Ford, M.S.; Muller-Dethlefs, K., The S1 neutral and D0 cationic states of fluorobenzene and fluorobenzene?argon probed by ZEKE spectroscopy with partial rotational resolution, Phys. Chem. Chem. Phys., 2004, 6, 1, 23, https://doi.org/10.1039/b312115a . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References