2-Hexene, 2,5-dimethyl-

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Kovats' RI, non-polar column, isothermal

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Petrocol DHSqualaneOV-101OV-101OV-101
Column length (m) 150.93.   
Carrier gas H2He   
Substrate      
Column diameter (mm) 0.250.25   
Phase thickness (μm) 1.    
Temperature (C) 30.30.40.60.80.
I 762.750.768.760.761.
ReferenceSoják, Addová, et al., 2004Soják, Addová, et al., 2004Laub and Purnell, 1988Laub and Purnell, 1988Laub and Purnell, 1988
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101OV-101SqualaneSqualaneDB-1
Column length (m) 100.100.100.100.60.
Carrier gas N2N2N2N2H2
Substrate      
Column diameter (mm) 0.270.270.250.250.264
Phase thickness (μm) 0.90.9  0.25
Temperature (C) 50.70.50.70.40.
I 759.760.749.8750.5762.
ReferenceBoneva and Dimov, 1986Boneva and Dimov, 1986Boneva and Dimov, 1986Boneva and Dimov, 1986Lubeck and Sutton, 1984
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-PONASqualaneSqualaneSqualaneSqualane
Column length (m) 50. 50.100.100.
Carrier gas H2 H2N2N2
Substrate      
Column diameter (mm) 0.21 0.20.250.25
Phase thickness (μm) 0.5    
Temperature (C) 40.50.100.50.70.
I 762.750.750.750.751.
ReferenceLubeck and Sutton, 1984Chretien and Dubois, 1976Mitra, Mohan, et al., 1974Rijks and Cramers, 1974Rijks and Cramers, 1974
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPackedPacked
Active phase SqualaneSqualaneSqualane
Column length (m) 91.410.10.
Carrier gas N2H2H2
Substrate    
Column diameter (mm) 0.25  
Phase thickness (μm)    
Temperature (C) 40.30.50.
I 750.749.5750.
ReferenceMatukuma, 1969Tourres, 1967Tourres, 1967
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Soják, Addová, et al., 2004
Soják, L.; Addová, G.; Kubinec, R.; Kraus, A.; Bohác, A., Capillary gas chromatography-mass spectrometry of all 93 acyclic octenes and their identification in fluid catalytic cracked gasoline, J. Chromatogr. A, 2004, 1025, 2, 237-253, https://doi.org/10.1016/j.chroma.2003.10.112 . [all data]

Laub and Purnell, 1988
Laub, R.J.; Purnell, J.H., Specific retention volumes, retention indices, and family-plot regressions of aliphatic, alicyclic, and aromatic hydrocarbon solutes with OV-101 poly (dimethylsiloxane) stationary phase, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1988, 11, 9, 649-660, https://doi.org/10.1002/jhrc.1240110908 . [all data]

Boneva and Dimov, 1986
Boneva, S.; Dimov, N., Gas Chromatographic Retention Indices for Alkenes on OV-101 and Squalane Capillary Columns, Chromatographia, 1986, 21, 3, 149-151, https://doi.org/10.1007/BF02311743 . [all data]

Lubeck and Sutton, 1984
Lubeck, A.J.; Sutton, D.L., Kovats Retention Indices of Selected Olefins on Bonded Phase Fused Silica Capillaries, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1984, 7, 9, 542-544, https://doi.org/10.1002/jhrc.1240070913 . [all data]

Chretien and Dubois, 1976
Chretien, J.R.; Dubois, J.-E., New Perspectives in the Prediction of Kovats Indices, J. Chromatogr., 1976, 126, 171-189, https://doi.org/10.1016/S0021-9673(01)84071-1 . [all data]

Mitra, Mohan, et al., 1974
Mitra, G.D.; Mohan, G.; Sinha, A., Gas chromatographic analysis of complex hydrocarbon mixtures, J. Chromatogr. A, 1974, 91, 633-648, https://doi.org/10.1016/S0021-9673(01)97944-0 . [all data]

Rijks and Cramers, 1974
Rijks, J.A.; Cramers, C.A., High precision capillary gas chromatography of hydrocarbons, Chromatographia, 1974, 7, 3, 99-106, https://doi.org/10.1007/BF02269819 . [all data]

Matukuma, 1969
Matukuma, A., Retention indices of alkanes through C10 and alkenes through C8 and relation between boiling points and retention data, Gas Chromatogr., Int. Symp. Anal. Instrum. Div Instrum Soc. Amer., 1969, 7, 55-75. [all data]

Tourres, 1967
Tourres, D.A., Structural analysis of industrial butene dimers by gas chromatography, J. Gas Chromatogr., 1967, 5, 1, 35-40, https://doi.org/10.1093/chromsci/5.1.35 . [all data]


Notes

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