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Trimethylindium


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas49.9 ± 2.4kcal/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafsolid38.3 ± 2.3kcal/molReviewMartinho Simões 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltasub11.6 ± 0.60kcal/molN/APilcher and Skinner, 1983See also Clark and Price, 1968.; AC
Deltasub11.6 ± 0.60kcal/molRSCDennis, Work, et al., 1934MS

Enthalpy of sublimation

DeltasubH (kcal/mol) Temperature (K) Method Reference Comment
15.0294.N/AFulem, Ruzicka, et al., 2004Based on data from 274. - 313. K.; AC
13.8344.AStephenson and Malanowski, 1987Based on data from 328. - 362. K. See also Laubengayer and Gilliam, 1941.; AC

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Reference Comment
3.4178358.7Ur'yash, Ronina, et al., 1991DH
3.42358.7Ur'yash, Ronina, et al., 1991, 2AC

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Trimethylindium (l) + 3Bromine (l) = Br3In (cr) + 3Methane, bromo- (g)

By formula: C3H9In (l) + 3Br2 (l) = Br3In (cr) + 3CH3Br (g)

Quantity Value Units Method Reference Comment
Deltar-159.0 ± 1.0kcal/molRSCClarke and Price, 1968Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Trimethylindium (g) = C2H6In (g) + Methane (g)

By formula: C3H9In (g) = C2H6In (g) + CH4 (g)

Quantity Value Units Method Reference Comment
Deltar49.0 - 52.1kcal/molN/ASmith and Patrick, 1983 
Deltar49.0 ± 4.0kcal/molN/AMcMillen and Golden, 1982 

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin MUS30 A. Mujsce, AT&T Bell Labs., Murray Hill, N.J., USA
NIST MS number 115426

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Clark and Price, 1968
Clark, W.D.; Price, S.J.W., Determination of the heat of formation of trimethylindium and calculation of the mean In---CH 3 bond dissociation energy, Can. J. Chem., 1968, 46, 10, 1633-1634, https://doi.org/10.1139/v68-272 . [all data]

Dennis, Work, et al., 1934
Dennis, L.M.; Work, R.W.; Rochow, E.G.; Chamot, E.M., J. Am. Chem. Soc., 1934, 56, 1047. [all data]

Fulem, Ruzicka, et al., 2004
Fulem, M.; Ruzicka, K.; Ruzicka, V.; Hulicius, E.; Simecek, T.; Pangrác, J.; Rushworth, S.A.; Smith, L.M., Measurement of vapour pressure of In-based metalorganics for MOVPE, Journal of Crystal Growth, 2004, 272, 1-4, 42-46, https://doi.org/10.1016/j.jcrysgro.2004.09.001 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Laubengayer and Gilliam, 1941
Laubengayer, A.W.; Gilliam, W.F., The Alkyls of the Third Group Elements. I. Vapor Phase Studies of the Alkyls of Aluminum, Gallium and Indium 1, J. Am. Chem. Soc., 1941, 63, 2, 477-479, https://doi.org/10.1021/ja01847a031 . [all data]

Ur'yash, Ronina, et al., 1991
Ur'yash, V.F.; Ronina, O.V.; Karataev, E.N.; Zimina, I.D., Physicochemical study of alkyl derivatives of indium, Metalloorg. Khim., 1991, 4(5), 1050-1054. [all data]

Ur'yash, Ronina, et al., 1991, 2
Ur'yash, V.F.; Ronina, O.V.; Karataev, E.N.; Zimina, I.V.; Kuznetsova, T.V.; Petrun, T.V.; Feshchenko, I.A.; Zorin, A.D., Physicochemical study of alkyl derivatives of indium, Metalloogranicheskaya Khimiya, 1991, 4, 5, 1050. [all data]

Clarke and Price, 1968
Clarke, W.D.; Price, S.J.W., Can. J. Chem., 1968, 46, 1633. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Smith and Patrick, 1983
Smith, G.P.; Patrick, R., Int. J. Chem. Kinet., 1983, 15, 167. [all data]

McMillen and Golden, 1982
McMillen, D.F.; Golden, D.M., Hydrocarbon bond dissociation energies, Ann. Rev. Phys. Chem., 1982, 33, 493. [all data]


Notes

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