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Ni(CO)


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CNiO (g) = Carbon monoxide (g) + nickel (g)

By formula: CNiO (g) = CO (g) + Ni (g)

Quantity Value Units Method Reference Comment
Deltar170. ± 24.kJ/molFA-SIFTSunderlin, Wang, et al., 1992 
Deltar108.kJ/molN/AMcQuaid, Morris, et al., 1988Method: Chemiluminescence spectroscopy.
Deltar121. ± 63.kJ/molN/AStevens, Feigerle, et al., 1982Please also see Compton and Stockdale, 1976. Method: LPS and collision with low energy electrons.

C2NiO2 (g) = CNiO (g) + Carbon monoxide (g)

By formula: C2NiO2 (g) = CNiO (g) + CO (g)

Quantity Value Units Method Reference Comment
Deltar197. ± 24.kJ/molFA-SIFTSunderlin, Wang, et al., 1992 
Deltar228. ± 63.kJ/molN/AStevens, Feigerle, et al., 1982Please also see Compton and Stockdale, 1976. Method: LPS and collision with low energy electrons.

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 11050 ± 240 gas Stevens, Feigerle, et al., 1982

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

1 CO stretch 2010.69 gas DL Martinez and Morse, 2006
1 CO stretch 2006.7 Ne IR Liang, Zhou, et al., 2000
Tremblay and Manceron, 2006
1 CO stretch 1994.5 vs Ar IR DeKock, 1971
Joly and Manceron, 1998
Zhou and Andrews, 1998
Tremblay and Manceron, 2006
Pi 2 Bend 398.9 w Ne IR Tremblay and Manceron, 2006
2 Bend 409.1 w Ar IR Joly and Manceron, 1998
Tremblay and Manceron, 2006
Sigma+ 3 NiC stretch 592.2 w Ne IR Tremblay and Manceron, 2006
3 NiC stretch 591.1 w Ar IR Joly and Manceron, 1998
Tremblay and Manceron, 2006

Additional references: Jacox, 1998, page 167; Jacox, 2003, page 67; Yamazaki, Okabayashi, et al., 2004

Notes

wWeak
vsVery strong
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Reaction thermochemistry data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sunderlin, Wang, et al., 1992
Sunderlin, L.S.; Wang, D.; Squires, R.R., Metal Carbonyl Bond Strengths in Fe(CO)n- and Ni(CO)n-, J. Am. Chem. Soc., 1992, 114, 8, 2788, https://doi.org/10.1021/ja00034a004 . [all data]

McQuaid, Morris, et al., 1988
McQuaid, M.J.; Morris, K.; Gole, J.L., J. Am. Chem. Soc., 1988, 110, 5280. [all data]

Stevens, Feigerle, et al., 1982
Stevens, A.E.; Feigerle, C.S.; Lineberger, W.C., Laser Photoelectron Spectrometry of Ni(CO)n-, n=1-3, J. Am. Chem. Soc., 1982, 104, 19, 5026, https://doi.org/10.1021/ja00383a004 . [all data]

Compton and Stockdale, 1976
Compton, R.N.; Stockdale, J.A.D., Formation of gas phase negative ions in Fe(CO)5 and Ni(CO)4, Int. J. Mass Spectrom. Ion Phys., 1976, 22, 47. [all data]

Martinez and Morse, 2006
Martinez, A.; Morse, M.D., Infrared diode laser spectroscopy of jet-cooled NiCO, Ni(CO)[sub 3]([sup 13]CO), and Ni(CO)[sub 3](C[sup 18]O), J. Chem. Phys., 2006, 124, 12, 124316, https://doi.org/10.1063/1.2180249 . [all data]

Liang, Zhou, et al., 2000
Liang, B.; Zhou, M.; Andrews, L., Reactions of Laser-Ablated Ni, Pd, and Pt Atoms with Carbon Monoxide: Matrix Infrared Spectra and Density Functional Calculations on M(CO), J. Phys. Chem. A, 2000, 104, 17, 3905, https://doi.org/10.1021/jp993646q . [all data]

Tremblay and Manceron, 2006
Tremblay, B.; Manceron, L., Search for the Ar--NiCO complex: A solid neon investigation, Chem. Phys. Lett., 2006, 429, 4-6, 464, https://doi.org/10.1016/j.cplett.2006.08.053 . [all data]

DeKock, 1971
DeKock, R.L., Preparation and identification of intermediate carbonyls of nickel and tantalum by matrix isolation, Inorg. Chem., 1971, 10, 6, 1205, https://doi.org/10.1021/ic50100a022 . [all data]

Joly and Manceron, 1998
Joly, H.A.; Manceron, L., Complete vibrational spectrum of NiCO isolated in solid argon, Chem. Phys., 1998, 226, 1-2, 61, https://doi.org/10.1016/S0301-0104(97)00312-1 . [all data]

Zhou and Andrews, 1998
Zhou, M.; Andrews, L., Matrix Infrared Spectra and Density Functional Calculations of Ni(CO), J. Am. Chem. Soc., 1998, 120, 44, 11499, https://doi.org/10.1021/ja9820644 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Yamazaki, Okabayashi, et al., 2004
Yamazaki, E.; Okabayashi, T.; Tanimoto, M., Detection of Free Nickel Monocarbonyl, NiCO: Rotational Spectrum and Structure, J. Am. Chem. Soc., 2004, 126, 4, 1028, https://doi.org/10.1021/ja0391309 . [all data]


Notes

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