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titanium tetrakis(dimethylammonium)


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-400. ± 110.kJ/molReviewMartinho Simões 
Deltafgas-210. ± 11.kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -1579.0 ± 3.9 kJ/mol for the enthalpy of formation of Ti(O-i-Pr)4(l)

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafliquid-460. ± 110.kJ/molReviewMartinho Simões 
Deltafliquid-268.8 ± 7.1kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -1579.0 ± 3.9 kJ/mol for the enthalpy of formation of Ti(O-i-Pr)4(l)
Quantity Value Units Method Reference Comment
Deltacliquid-7070. ± 110.kJ/molCC-SBMakhailov, Baev, et al., 1986 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Deltavap58.6 ± 8.4kJ/molCC-SBLappert, Patil, et al., 1975MS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Reference Comment
53.8 ± 3.0383.Baev, Mikhailov, et al., 1984Based on data from 353. - 418. K. See also Baev and Mikhailov, 2001.; AC

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Makhailov, Baev, et al., 1986
Makhailov, V.E.; Baev, A.K.; Sachek, A.I.; Al'khimovich, V.M., Zh. Fiz. Khim., 1986, 60, 2306. [all data]

Lappert, Patil, et al., 1975
Lappert, M.F.; Patil, D.S.; Pedley, J.B., J. Chem. Soc., Chem. Commun., 1975, 830.. [all data]

Baev, Mikhailov, et al., 1984
Baev, A.K.; Mikhailov, V.E.; Baev, A.A., Vestsi Akad. Navuk BSSR Ser. Khim. Navuk, 1984, 75. [all data]

Baev and Mikhailov, 2001
Baev, A.K.; Mikhailov, V.E., Russian Journal of Applied Chemistry, 2001, 74, 9, 1435-1438, https://doi.org/10.1023/A:1013772227611 . [all data]


Notes

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