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HOSO2


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(HO4S- bullet 2Sulfuric Acid) + HO3S = (HO4S- bullet HO3S bullet 2Sulfuric Acid)

By formula: (HO4S- bullet 2H2O4S) + HO3S = (HO4S- bullet HO3S bullet 2H2O4S)

Quantity Value Units Method Reference Comment
Deltar87.9kJ/molATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated
Deltar75.kJ/molATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated, DG>, «DELTA»rH>
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/AArnold and Qiu, 1984gas phase; Entropy change calculated or estimated
Deltar100.J/mol*KN/AArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated, DG>, «DELTA»rH>

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
61.9250.ATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated
50.233.ATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated, DG>, «DELTA»rH>

HO4S- + HO3S = (HO4S- bullet HO3S)

By formula: HO4S- + HO3S = (HO4S- bullet HO3S)

Quantity Value Units Method Reference Comment
Deltar93.7kJ/molATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated, DG>, «DELTA»rH>
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/AArnold and Qiu, 1984gas phase; Entropy change calculated or estimated, DG>, «DELTA»rH>

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
67.8250.ATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated, DG>, «DELTA»rH>

(H2O4S- bullet Sulfuric Acid) + HO3S = (H2O4S- bullet HO3S bullet Sulfuric Acid)

By formula: (H2O4S- bullet H2O4S) + HO3S = (H2O4S- bullet HO3S bullet H2O4S)

Quantity Value Units Method Reference Comment
Deltar92.5kJ/molATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/AArnold and Qiu, 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
66.5250.ATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated

(HO4S- bullet Nitric acid) + HO3S = (HO4S- bullet HO3S bullet Nitric acid)

By formula: (HO4S- bullet HNO3) + HO3S = (HO4S- bullet HO3S bullet HNO3)

Quantity Value Units Method Reference Comment
Deltar90.8kJ/molATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/AArnold and Qiu, 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
64.9250.ATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Arnold and Qiu, 1984
Arnold, F.; Qiu, S., Upper Stratosphere Negative Ion Composition Measurements and Infrared Trace Gas Abundances, Planet. Space Sci., 1984, 32, 2, 169, https://doi.org/10.1016/0032-0633(84)90151-X . [all data]

Arnold, Viggiano, et al., 1982
Arnold, F.; Viggiano, A.A.; Schlager, H., Implications for Trace Gases and Aerosols of Large Negative Ions Clusters in the Stratosphere, Nature, 1982, 297, 5865, 371, https://doi.org/10.1038/297371a0 . [all data]


Notes

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