Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to Sb2+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
1.2820 ± 0.0080LPESPolak, Gerber, et al., 1992B

Ionization energy determinations

IE (eV) Method Reference Comment
<=8.43PIYoo, Ruscic, et al., 1993LL
8.3EIBusse and Weil, 1982LBLHLM
8.9 ± 0.3EIKordis and Gingerich, 1973LLK
8.64 ± 0.06EICabaud, Hoareau, et al., 1973LLK
9.3 ± 0.2SDonovan and Strachan, 1971LLK
8.7 ± 0.3EIKohl, Prusaczyk, et al., 1967RDSH
9.5 ± 0.5EIGutbier, 1961RDSH
8.4 ± 0.3EIDeMaria, Drowart, et al., 1959RDSH
8.7PIYoo, Ruscic, et al., 1993Vertical value; LL

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Sb+11.4SbEIBusse and Weil, 1982LBLHLM
Sb+11.5 ± 0.5SbEIPiacente and Balducci, 1974LLK
Sb+9.3 ± 0.3?EIKohl, Prusaczyk, et al., 1967RDSH
Sb+11.5 ± 0.3SbEIDeMaria, Drowart, et al., 1959RDSH


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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Polak, Gerber, et al., 1992
Polak, M.L.; Gerber, G.; Ho, J.; Lineberger, W.C., Photoelectron Spectroscopy of Small Antimony Cluster Anions - Sb(-) Sb2(-), Sb3(-), and Sb4(-), J. Chem. Phys., 1992, 97, 12, 8990, https://doi.org/10.1063/1.463326 . [all data]

Yoo, Ruscic, et al., 1993
Yoo, R.K.; Ruscic, B.; Berkowitz, J., Photoionization mass spectrometric studies of Sb2 and Bi2, J. Chem. Phys., 1993, 99, 8445. [all data]

Busse and Weil, 1982
Busse, B.; Weil, K.G., Mass spectrometric studies on the vapour phase composition over solid and fused Cs3Sb, Ber. Bunsen-Ges. Phys. Chem., 1982, 86, 93. [all data]

Kordis and Gingerich, 1973
Kordis, J.; Gingerich, K.A., Mass spectroscopic investigation of the equilibrium dissociation of gaseous Sb2, Sb3, Sb4, SbP, SbP3, and P2, J. Chem. Phys., 1973, 58, 5141. [all data]

Cabaud, Hoareau, et al., 1973
Cabaud, B.; Hoareau, A.; Nounou, P.; Uzan, R., High temperature mass spectrometric study of polyatomic antimony species by electron impact. Direct evidence for the existence of Sb3 molecules, Int. J. Mass Spectrom. Ion Phys., 1973, 11, 157. [all data]

Donovan and Strachan, 1971
Donovan, R.J.; Strachan, P., Vacuum U.-V. spectra of transient molecules and radicals, J. Chem. Soc. Faraday Trans., 1971, 67, 3407. [all data]

Kohl, Prusaczyk, et al., 1967
Kohl, F.J.; Prusaczyk, J.E.; Carlson, K.D., New gaseous molecules of the pnictides, J. Am. Chem. Soc., 1967, 89, 5501. [all data]

Gutbier, 1961
Gutbier, H., Massenspektrometrische Untersuchungen der Verdampfungsvorgange bei einigen Verbindungen mit Zinkblende-Gitter im Temperaturbereich um 1000 degree K, Z. Naturforsch. A:, 1961, 16, 268. [all data]

DeMaria, Drowart, et al., 1959
DeMaria, G.; Drowart, J.; Inghram, M.G., Thermodynamic study of InSb with a mass spectrometer, J. Chem. Phys., 1959, 31, 1076. [all data]

Piacente and Balducci, 1974
Piacente, V.; Balducci, G., The dissociation energy of the molecule GaSb, High Temp. Sci., 1974, 6, 254. [all data]


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