Adenosine, N-(trimethylsilyl)-2',3'-bis-O-(trimethylsilyl)-, 5'-[bis(trimethylsilyl) phosphate]
- Formula: C25H54N5O7PSi5
- Molecular weight: 708.1268
- IUPAC Standard InChI: InChI=1S/C25H54N5O7PSi5/c1-39(2,3)29-23-20-24(27-17-26-23)30(18-28-20)25-22(35-41(7,8)9)21(34-40(4,5)6)19(33-25)16-32-38(31,36-42(10,11)12)37-43(13,14)15/h17-19,21-22,25H,16H2,1-15H3,(H,26,27,29)
- IUPAC Standard InChIKey: SUBGEEAXSQFRTK-UHFFFAOYSA-N
- CAS Registry Number: 32653-14-8
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: 5'-Adenylic acid, N-(trimethylsilyl)-2',3'-bis-O-(trimethylsilyl)-, bis(trimethylsilyl) ester; Adenosine-5'-monophosphate, pentakis-TMS; adenosine-5'-monophosphate, TMS; Adenosine-5-monophosphate, N,O-5TMS; Adenosine-5'-monophosphate, pentakis-N,O,O,O,O-TMS
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Mass spectrum (electron ionization)
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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| Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
|---|---|
| Origin | J.A.MCCLOSKEY,BAYLOR COL OF MEDICIN,HOUSTON,TEX.77025 |
| NIST MS number | 24988 |
Gas Chromatography
Go To: Top, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Packed | SE-30 | 3114. | Butts, 1970 | He, Chromosorb W; Column length: 2. m; Program: not specified |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Methylsiloxane, 5 % Ph groups | 3115. | Cao, Aa, et al., 2011 | Program: not specified |
References
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Butts, 1970
Butts, W.C.,
Gas chromatographic separation of trimethylsilyl (TMS)-nucleosides: TMS-methoxime derivatives of cytidine and deoxycytidine,
J. Chromatogr. Sci., 1970, 8, 8, 474-476, https://doi.org/10.1093/chromsci/8.8.474
. [all data]
Cao, Aa, et al., 2011
Cao, B.; Aa, J.; Wang, G.; Wu, X.; Liu, L.; Li, M.; Shi, J.; Wang, X.; Zhao, C.; Zheng, T.; Guo, S.; Duan, J.,
GC-TOFMS analysis of metabolites in adherent MDCK cells and a movel strategy for identifying intracellular metabolic markers for use as cell amount indicators in data normalization,
Anal. Bioanal. Chem., 2011, 400, 9, 2983-2993, https://doi.org/10.1007/s00216-011-4981-8
. [all data]
Notes
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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