Nickel acetylacetonate

• Formula: C₁₀H₁₄NiO₄
• Molecular weight: 256.9092
• IUPAC Standard InChI: InChI=1S/2C5H8O2.Ni/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-; Copy

  
• IUPAC Standard InChIKey: BMGNSKKZFQMGDH-FDGPNNRMSA-L Copy
• CAS Registry Number: 3264-82-2
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Nickel, bis(2,4-pentanedionato-O,O')-, (SP-4-1)-; Nickel, bis(2,4-pentanedionato)-; Acetylacetonato nickel; Bis(acetylacetonate)nickel; Bis(acetylacetonato)nickel; Bis(2,4-pentanedionato)nickel; Bis-2,4-pentanedionatonickel(II); Ni(II) Acetylacetone complex (1:2); Nickel acetonylacetonate; Nickel bis(acetylacetonate); Nickel bis(2,4-pentanedionate); Nickel(II) acetylacetonate; Nickel(2+) acetylacetonate; Nickelous acetylacetonate; Nickel(II) 2,4-pentanedionate; Bis(acetylacetonato)nickel(II); Acetylacetonatonickel (II); Bis(acetylacetone)nickel; NSC 4657; bis(pentane-2,4-dionato-O,O')nickel
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • References
  • Notes
• Data at other public NIST sites:
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Condensed Phase Spectrum

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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Malkerova, Alikhanyan, et al., 1990
Malkerova, I.P.; Alikhanyan, A.S.; Sevast'yanov, V.G.; Grinberg, Ya.Kh.; Gorgoraki, V.I., Thermal behavior of 3d transition metal acetylacetonates, Zh. Neorg. Khim., 1990, 35, 2, 413. [all data]

Murata, Sakiyama, et al., 1985
Murata, S.; Sakiyama, M.; Seki, S., Sublimation calorimetric studies using a calvet microcalorimeter, Thermochimica Acta, 1985, 88, 1, 121-126, https://doi.org/10.1016/0040-6031(85)85419-8 . [all data]

Burkinshaw and Mortimer, 1984
Burkinshaw, Philip M.; Mortimer, Colin T., Enthalpies of sublimation of transition metal complexes, J. Chem. Soc., Dalton Trans., 1984, 1, 75, https://doi.org/10.1039/dt9840000075 . [all data]

Murray and Hill, 1987
Murray, J.P.; Hill, J.O., DSC determination of the sublimation enthalpy of tris(2,4-pentanedionato)cobalt(III) and bis(2,4-pentanedionato) nickel(II) and -copper(II), Thermochimica Acta, 1987, 109, 2, 383-390, https://doi.org/10.1016/0040-6031(87)80034-5 . [all data]

Ribeiro Da Silva and Ferrão, 1987
Ribeiro Da Silva, Manuel A.V.; Ferrão, Maria Luísa C.C.H., Standard enthalpies of formation of tris(β-diketonate)chromium(III) complexes: the mean (Cr«58872»O) bond-dissociation enthalpies, The Journal of Chemical Thermodynamics, 1987, 19, 6, 645-652, https://doi.org/10.1016/0021-9614(87)90070-X . [all data]

Götze, Bloss, et al., 1970
Götze, H.-J.; Bloss, K.; Molketin, H., Dampfdruckbestimmung von Acetylacetonaten, Zeitschrift für Physikalische Chemie, 1970, 73, 4₆, 314-320, https://doi.org/10.1524/zpch.1970.73.4₆.314 . [all data]

Reichert and Westmore, 1969
Reichert, C.; Westmore, J.B., Mass spectral studies of metal chelates. IV.Mass spectra, appearance potentials, and coordinate bond energies of bis(acetylacetonate)metal(II) complexes of the first transition series, Inorg. Chem., 1969, 8, 1012. [all data]

Kitagawa, Morishima, et al., 1983
Kitagawa, S.; Morishima, I.; Yoshikawa, K., UV photoelectron spectra of some transition metal(II)aAcetylacetonates, Polyhedron, 1983, 2, 43. [all data]

Fragala, Costanzo, et al., 1980
Fragala, I.; Costanzo, L.L.; Ciliberto, E.; Condorelli, G.; D'Arrigo, C., He-I and He-II excited photoelectron spectra of tetracoordinated complexes of transition metal ions with β-diketonate ligands, Inorg. Chim. Acta, 1980, 40, 15. [all data]

Cauletti, Furlani, et al., 1980
Cauletti, C.; Furlani, C.; Storto, G., Coordinative bond d-shell ionisations in the UV photoelectron spectra of bis({beta}-diketonato) cobalt (II) copper (II) complexes, their thio analogues, J. Electron Spectrosc. Relat. Phenom., 1980, 18, 329. [all data]

Cauletti and Furlani, 1975
Cauletti, C.; Furlani, C., He(I) photoelectron spectra of bis(β-diketonate)nickel(II) complexes their and mono- and di-thio analogues, J. Electron Spectrosc. Relat. Phenom., 1975, 6, 465. [all data]

Brittain and Disch, 1975
Brittain, H.G.; Disch, R.L., The He(I) photoelectron spectra of some bivalent transition metal β-diketonate complexes*, J. Electron Spectrosc. Relat. Phenom., 1975, 7, 475. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  ΔsubH	Enthalpy of sublimation
  ΔsubH°	Enthalpy of sublimation at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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