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Nickel acetylacetonate


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Deltasub126.4 ± 4.4kJ/molMEMalkerova, Alikhanyan, et al., 1990Based on data from 357. - 420. K.
Deltasub155. ± 80.kJ/molCMurata, Sakiyama, et al., 1985 
Deltasub132. ± 10.kJ/molMEBurkinshaw and Mortimer, 1984 

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
108. ± 5.207.DSCMurray and Hill, 1987 
108.2 ± 4.9480.DSCRibeiro Da Silva and Ferrão, 1987 
128. ± 10.381.MEBurkinshaw and Mortimer, 1984Based on data from 378. - 403. K.
95.4400.N/AGötze, Bloss, et al., 1970 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.23 ± 0.05EIReichert and Westmore, 1969RDSH
7.62PEKitagawa, Morishima, et al., 1983Vertical value; LBLHLM
7.35PEFragala, Costanzo, et al., 1980Vertical value; LLK
7.40PECauletti, Furlani, et al., 1980Vertical value; LLK
7.41PECauletti and Furlani, 1975Vertical value; LLK
7.61PEBrittain and Disch, 1975Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C5H7O2Ni+13.5 ± 0.2?EIReichert and Westmore, 1969RDSH
C9H11O4Ni+11.6 ± 0.1?EIReichert and Westmore, 1969RDSH

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Condensed Phase Spectrum

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IR spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

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Owner COBLENTZ SOCIETY
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin STANDARD OIL OF OHIO
Source reference COBLENTZ NO. 196
Date Not specified, most likely prior to 1970
State SOLID (0.5% IN KBr PELLET)
Instrument Not specified, most likely a grating spectrometer.
Resolution 4
Sampling procedure TRANSMISSION
Data processing DIGITIZED BY NIST FROM HARD COPY

This IR spectrum is from the Coblentz Society's evaluated infrared reference spectra collection.


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 157252

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Malkerova, Alikhanyan, et al., 1990
Malkerova, I.P.; Alikhanyan, A.S.; Sevast'yanov, V.G.; Grinberg, Ya.Kh.; Gorgoraki, V.I., Thermal behavior of 3d transition metal acetylacetonates, Zh. Neorg. Khim., 1990, 35, 2, 413. [all data]

Murata, Sakiyama, et al., 1985
Murata, S.; Sakiyama, M.; Seki, S., Sublimation calorimetric studies using a calvet microcalorimeter, Thermochimica Acta, 1985, 88, 1, 121-126, https://doi.org/10.1016/0040-6031(85)85419-8 . [all data]

Burkinshaw and Mortimer, 1984
Burkinshaw, Philip M.; Mortimer, Colin T., Enthalpies of sublimation of transition metal complexes, J. Chem. Soc., Dalton Trans., 1984, 1, 75, https://doi.org/10.1039/dt9840000075 . [all data]

Murray and Hill, 1987
Murray, J.P.; Hill, J.O., DSC determination of the sublimation enthalpy of tris(2,4-pentanedionato)cobalt(III) and bis(2,4-pentanedionato) nickel(II) and -copper(II), Thermochimica Acta, 1987, 109, 2, 383-390, https://doi.org/10.1016/0040-6031(87)80034-5 . [all data]

Ribeiro Da Silva and Ferrão, 1987
Ribeiro Da Silva, Manuel A.V.; Ferrão, Maria Luísa C.C.H., Standard enthalpies of formation of tris(«beta»-diketonate)chromium(III) complexes: the mean (Cr«58872»O) bond-dissociation enthalpies, The Journal of Chemical Thermodynamics, 1987, 19, 6, 645-652, https://doi.org/10.1016/0021-9614(87)90070-X . [all data]

Götze, Bloss, et al., 1970
Götze, H.-J.; Bloss, K.; Molketin, H., Dampfdruckbestimmung von Acetylacetonaten, Zeitschrift für Physikalische Chemie, 1970, 73, 46, 314-320, https://doi.org/10.1524/zpch.1970.73.46.314 . [all data]

Reichert and Westmore, 1969
Reichert, C.; Westmore, J.B., Mass spectral studies of metal chelates. IV.Mass spectra, appearance potentials, and coordinate bond energies of bis(acetylacetonate)metal(II) complexes of the first transition series, Inorg. Chem., 1969, 8, 1012. [all data]

Kitagawa, Morishima, et al., 1983
Kitagawa, S.; Morishima, I.; Yoshikawa, K., UV photoelectron spectra of some transition metal(II)aAcetylacetonates, Polyhedron, 1983, 2, 43. [all data]

Fragala, Costanzo, et al., 1980
Fragala, I.; Costanzo, L.L.; Ciliberto, E.; Condorelli, G.; D'Arrigo, C., He-I and He-II excited photoelectron spectra of tetracoordinated complexes of transition metal ions with «beta»-diketonate ligands, Inorg. Chim. Acta, 1980, 40, 15. [all data]

Cauletti, Furlani, et al., 1980
Cauletti, C.; Furlani, C.; Storto, G., Coordinative bond d-shell ionisations in the UV photoelectron spectra of bis({beta}-diketonato) cobalt (II) copper (II) complexes, their thio analogues, J. Electron Spectrosc. Relat. Phenom., 1980, 18, 329. [all data]

Cauletti and Furlani, 1975
Cauletti, C.; Furlani, C., He(I) photoelectron spectra of bis(«beta»-diketonate)nickel(II) complexes their and mono- and di-thio analogues, J. Electron Spectrosc. Relat. Phenom., 1975, 6, 465. [all data]

Brittain and Disch, 1975
Brittain, H.G.; Disch, R.L., The He(I) photoelectron spectra of some bivalent transition metal «beta»-diketonate complexes*, J. Electron Spectrosc. Relat. Phenom., 1975, 7, 475. [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References