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GaOH


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 39000 Ar A-X Douglas, Hauge, et al., 1983
Tx = 39000 Kr A-X Douglas, Hauge, et al., 1983

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 OH stretch 3689.8 Ar IR Hauge, Kauffman, et al., 1980
Macrae and Downs, 2004
Wang and Andrews, 2007
Pi 2 Bend 425.5 Ar IR Hauge, Kauffman, et al., 1980
Macrae and Downs, 2004
Sigma+ 3 GaO stretch 613.2 Ar IR Hauge, Kauffman, et al., 1980
Macrae and Downs, 2004
Wang and Andrews, 2007

Additional references: Jacox, 1994, page 36

Notes

xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Douglas, Hauge, et al., 1983
Douglas, M.A.; Hauge, R.H.; Margrave, J.L., J. Chem. Soc., 1983, Faraday Trans. 1 79, 1533. [all data]

Hauge, Kauffman, et al., 1980
Hauge, R.H.; Kauffman, J.W.; Margrave, J.L., Infrared matrix-isolation studies of the interactions and reactions of Group 3A metal atoms with water, J. Am. Chem. Soc., 1980, 102, 19, 6005, https://doi.org/10.1021/ja00539a005 . [all data]

Macrae and Downs, 2004
Macrae, V.A.; Downs, A.J., Matrix studies of the thermal and photolytic reactions of Ga vapour species with H2O: formation and characterisation of the adducts Ga«65533»OH2 and Ga2«65533»OH2 and the photoproducts HGaOH, GaOH and Ga(«65533»-H)(«65533»-OH)GaElectronic supplementary information (ESI) available: UV?vis spectra of an Ar matrix containing Ga and H2O (Fig. S1); calculated and observed IR spectral details for Ga(«65533»-H)(«65533»-OH)Ga (Table S1). See http://www.rsc.org/suppdata/cp/b4/b405298f/, Phys. Chem. Chem. Phys., 2004, 6, 19, 4571, https://doi.org/10.1039/b405298f . [all data]

Wang and Andrews, 2007
Wang, X.; Andrews, L., Infrared Spectroscopic Observation of the Group 13 Metal Hydroxides, M(OH), J. Phys. Chem. A, 2007, 111, 10, 1860, https://doi.org/10.1021/jp066390e . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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