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2-Cyano-2-propyl radical


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to C4H6N+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
1.08 ± 0.13D-EABartmess, Scott, et al., 1979value altered from reference due to change in acidity scale; B

Ionization energy determinations

IE (eV) Method Reference Comment
8.2PEKoenig, Snell, et al., 1976LLK
9.2 ± 0.1EIPottie and Lossing, 1961RDSH
8.56 ± 0.06PEKoenig, Snell, et al., 1976Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bartmess, Scott, et al., 1979
Bartmess, J.E.; Scott, J.A.; McIver, R.T., Jr., The gas phase acidity scale from methanol to phenol, J. Am. Chem. Soc., 1979, 101, 6047. [all data]

Koenig, Snell, et al., 1976
Koenig, T.; Snell, W.; Chang, J.C., The He(I) photoelectron spectra of benzyl and «alpha»-cyanoisopropyl radicals, Tetrahedron Lett., 1976, 50, 4569. [all data]

Pottie and Lossing, 1961
Pottie, R.F.; Lossing, F.P., Free radicals by mass spectrometry. XXV. Ionization potentials of cyanoalkyl radicals, J. Am. Chem. Soc., 1961, 83, 4737. [all data]


Notes

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